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Henin will now play either Svetlana Kuznetsova of Alona Bondarenko who play in the other semi-final.
BBC: SPORT | Tennis | Henin & Bondarenko make J&S final
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Her next opponent is unseeded Ukrainian Alona Bondarenko, who battled past Lucie Safarova of the Czech Republic 5-7 6-4 7-5.
CNN: No. 1 Safina first to reach WTA showpiece
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Jankovic was broken twice in defeating Alona Bondarenko of Ukraine 6-2 6-0, while Ivanovic dispatched Nathalie Dechy of France 6-1 6-1.
BBC: SPORT | Tennis | Petrova and Williams both advance
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World number one Jankovic, the top player in the absence through injury of compatriot Ana Ivanovic, brushed aside Ukraine's Alona Bondarenko 7-5 6-1.
CNN: Federer, Nadal and Djokovic cruise through
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Meanwhile, Zheng Jie became the first Chinese player to make the last eight of the Australian Open by beating Ukraine's Alona Bondarenko 7-6 6-4.
CNN: Tennis: Returning Henin battles on
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Estonian 15th seed Kaia Kanepi suffered a 6-3 7-6 (7-4) reverse against Czech Lucie Safarova, who earned a second-round clash with Ukrainian Alona Bondarenko.
CNN: Sharapova on song as L.A. seeds tumble
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Former world No. 1 Jankovic, who reached the semifinals in Melbourne two years ago, was crushed 6-2 6-3 by Ukrainian 31st seed Alona Bondarenko.
CNN: STORY HIGHLIGHTS
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They were joined in the second round by Francesca Schiavone (17), Alona Bondarenko (27) and Alexandra Dulgheru (31), who were all taken to three sets before triumphing.
BBC: Serena Williams and Caroline Wozniacki make progress
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Murray went through with a four-set win over Robert Kendrick - while Baltacha , who reached the third round in 2002, beat Ukraine's Alona Bondarenko in three sets in a late-night match.
BBC: Six Brits lose on disastrous day
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Seventh seed Vera Zvonareva defeated ninth seed Alona Bondarenko 6-2 6-1, 13th seed Melanie Oudin beat Christina Mchale 6-4 6-0, and eighth seed Daniela Hantuchova battled past Angelique Kerber 6-7 (6-8) 7-5 6-3.
BBC: Caroline Wozniacki beats Patty Schnyder in Charleston
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Pennetta helped defending champions Italy to end the day level 1-1 with Ukraine, beating Kateryna Bondarenko 7-5 6-3 after Francesca Schiavone lost the opening match 6-1 6-4 to the elder Bondarenko sister Alona in Kharkiv.
CNN: Injured Serena to miss Paris tournament