研究结果表明胺可以作为价廉和高效的配体促进钯催化交叉偶联反应。
The results show that amine could be used as the inexpensive and highly efficient ligands to promote the palladium-catalyzed coupling reactions.
方法用p,O双齿螯合钯配合物催化偶联反应合成目标化合物。
METHODS the target compound was synthesized from cross-coupling reaction catalyzed by p, o chelate palladium complex.
在固定床反应器中对钯系催化剂上CO气相催化偶联制草酸二乙酯和草酸二甲酯的空时收率、选择性和CO的转化率进行了实验研究。
The synthesis of dimethyl oxalate (DMO) and diethyl oxalate (DEO) by CO coupling reaction in gaseous phase over the supported palladium catalysts was investigated.
制备了以超细二氧化硅为载体的氰乙基化可溶性蛋白质-钯催化剂,研究了它对三丁基锡氢化物和酰氯化合物偶联反应的催化活性。
Silica supported cyanoethylated soluble protein-Pd has been prepared and its catalytic activity in the cross-coupling reaction of tributyltin hydride and acid chlorides was studied.
芳基硼酸在三苯基膦钯催化下,与溴代芳烃偶联反应,得到较高收率的不对称联苯衍生物。
Four unsymmetrical biphenyl derivatives were synthesized with good yields by the tetrakis(triphenylphosphine) palladium (0) catalysed cross-coupling reaction of arylboronic acid with bromobenzene.
对偶联反应用钯催化剂的研究进行了综述。
Recent advances in palladium catalysts for coupling reaction of aryl chlorides were reviewed.
报道了纤维素氧膦 -钯配合物在有机锡试剂与酰氯化合物形成碳 -碳键的交叉偶联反应中的催化作用 ,并对部分反应条件及反应机理进行了研究和探讨。
The catalytic action of cellulose oxyphosphine palladium complexs in the crosscoupling reaction of organotin reagents with acid chlorides for forming C-C bond is presented.
报道了纤维素氧膦 -钯配合物在有机锡试剂与酰氯化合物形成碳 -碳键的交叉偶联反应中的催化作用 ,并对部分反应条件及反应机理进行了研究和探讨。
The catalytic action of cellulose oxyphosphine palladium complexs in the crosscoupling reaction of organotin reagents with acid chlorides for forming C-C bond is presented.
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