预测了金属卟啉化合物在催化领域的应用前景。
The future application of metalloporphyrins in catalysis is prospected.
在自然界中，大多数金属卟啉与蛋白质结合形成许多重要的分子，如细胞色素。
In nature, the majority of metalloporphyrins are conjugated to proteins to form a number of very important molecules, such as the cytochromes.
以2 8篇文献综述了金属卟啉模拟酶催化氧化饱和碳原子官能团化的研究进展。
Studying development of functionalization of saturated carbon by catalytic oxidation wit metalloporphyrins as a mimic of the enzyme cytochrome P-450 was reviewed with 28 references.
介绍了金属卟啉配合物在分子形状与大小识别、官能团识别和手性识别方面的研究概况。
Molecular recognition of size and shape, functional group, as well as chirality of guests by metalloporphyrin hosts are discussed in detail.
在壳聚糖四苯基金属卟啉中，氨基或羟基可能对金属卟啉的稳定性和催化活性起重要作用。
The amino groups or the hydroxyl groups on the chitosan-supported metal tetraphenylporphyrins may play a key role in improving the stability and the catalytic activity of metalloporphyrins.
与其他金属卟啉相比，铁卟啉的催化活性普遍较好，对硝基苯甲酸的收率都在75%以上。
And generally, the catalytic activity of iron porphyrins was better than that of other metal porphyrins, and the yields of PNBA are all more than 75%.
用固载金属卟啉模拟细胞色素P- 450单加氧酶体系，具有重要的学术价值和应用前景。
Modeling cytochrome P-450 monooxygenase with supported metalloporphyrins is very useful in research and application of them.
金属卟啉配合物的生物功能与其轴向配位现象是有着密切的联系的，轴向配位是金属卟啉的重要性质。
The biological functions of metalloporphyrin complexes have relationship with their axial coordination. The axial coordination of metalloporphyrin is its important character.
综述了金属卟啉在分子电子学，如分子存储、分子识别、图象传感、生物传感和化学传感等方面的研究及应用。
This paper reviews the study and application of metalloporphyrins in molecular electronics, such as molecular memory, molecular recognition, picture sensors, biosensors and chemical sensors.
评述了卟啉及金属卟啉化合物在合成及应用方面的研究进展，并简要介绍了卟啉及金属卟啉化合物的结构、性质。
The research development of porphyrins and metalloporphyrins was reviewed in this paper. The structure, properties, synthesis and applications of them were summarized.
合成了三种与咪唑配体键合的新型载体，并通过其与四苯基卟啉铁和卟啉锰配位得到了改性的负载金属卟啉催化剂。
Three new supporters bonded with ligand imidazole have been prepared. Modified catalysts of metalloporphyrins have been obtained by coordination of TPPFeCl or TPPMnCl with supporters.
为了深入了解金属卟啉醋酸钻复合催化对二甲苯反应机理及反应中各因素是如何影响反应速率的，我们必须研究反应动力学。
To gain better insight into the reaction mechanism and identify the effects of different parameters on the progress of the reaction, it is essential to study the kinetics.
在无任何外加溶剂及共还原剂的条件下，应用此高分子金属卟啉作为催化剂，选择性地催化空气氧化环己烷为环己酮和环己醇。
This macromolecular metalloporphyrin was used as the catalyst for the first time for cyclohexane oxidation to cyclohexanol and cyclohexanone with air in the absence of additives or solvents.
重点阐述了氯代苯甲酸的一系列合成方法，并简要介绍了金属卟啉模拟酶仿生催化氧气氧化氯代甲苯绿色合成氯代苯甲酸的新方法。
And gave a brief introduction of a novel technology for green synthesis of chlorobenzoic acids by dioxygen oxidation of chlorotoluenes using metalloporphyrins as biomimetic-catalysis.
重点阐述了氯代苯甲酸的一系列合成方法，并简要介绍了金属卟啉模拟酶仿生催化氧气氧化氯代甲苯绿色合成氯代苯甲酸的新方法。
And gave a brief introduction of a novel technology for green synthesis of chlorobenzoic acids by dioxygen oxidation of chlorotoluenes using metalloporphyrins as biomimetic-catalysis.
应用推荐