本文报道了以邻氯甲苯为原料,经光氯化、水解、取代三步合成2-甲酰基苯磺酸钠的方法,并对影响反应收率的因素进行了讨论。
Sodium 2-formylbenzenesulfonate was prepared from 2-chlorotoluene by photo-chlorination, hydrolysis and substitution reactions successively. Factors affecting the yields were discussed.
对甲苯磺酰基酰胺和2-苯基-N,N'-二甲基苯并咪唑啉(PDMBI)之间的光诱导电子转移反应,为酰胺的保护基——对甲苯磺酰基的脱除反应,提供了一条有效途径。
The photoinduced electron transfer reaction between N-tosyl amides and 2-phenyl-N, N'-dimethyl benzimidazoline (PDMBI) provides an efficient approach for the deprotection of N-tosyl amides.
对甲苯磺酰基酰胺和2-苯基-N,N'-二甲基苯并咪唑啉(PDMBI)之间的光诱导电子转移反应,为酰胺的保护基——对甲苯磺酰基的脱除反应,提供了一条有效途径。
The photoinduced electron transfer reaction between N-tosyl amides and 2-phenyl-N, N'-dimethyl benzimidazoline (PDMBI) provides an efficient approach for the deprotection of N-tosyl amides.
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