就像我说过的,我就可以计算所有的热力学量,如果我知道了配分函数。
Like I promised, we're going to be able to derive every thermodynamic quantity if we just know the partition function.
所以能够利用G写出任意一个热力学函数。
什么热力学量,是V,N和T的自然函数?
What thermodynamic function is naturally a function of N, V, T?
因为所有的热力学量都是态函数。
并从色谱热力学函数分析了保留指数随温度变化规律的主要原因是由于在色谱分离过程中不同的熵变和焓变所造成的。
The changing law of retention index with temperature from chromatographic thermal function resulted from the variation of the different entropy and enthalpy during the chromatographic separation.
他们的作用是描述,随着状态函数和状态变量的变化, 系统的热力性质如何变化。
So what they do is, they're describing how these thermodynamic properties change, in terms of only state functions and state variables.
通过多年教学实践,归纳出热力学函数间基本关系式的图示法。
Based on pedagogical experience, a scheme of diagrammatic representation of fundamental dependent equations relating thermodynamic functions is suggested.
根据等效焓降法在热力系统计算时的特点,推导了循环函数法在回热系统中的局部定量计算方法,导出了回热系统局部定量计算的几个重要结论。
According to the features of equivalent enthalpy-drop method applied to thermodynamic system, the methods of local quantitative calculation for cycle function method in regenerative system is deduced.
该模型以熵增加函数为基础,通过熵增加函数推导出热力学一致性的相场控制方程。
The entropy increase function, we has derived the phase field controlling equations which are thermodynamical consistent.
在热力学中,我们经常涉及两个或更多变量的函数。
In thermodynamics we usually deal with functions of two or more variables.
如果有一个物理量,对任何闭合回路积分是常数,这个物理量就是一个热力学态函数。
If you have a quantity which is constant over any closed path, that quantity is a thermodynamics state function.
本文试图在此基础上,综合地介绍表示几个热力学函数间关系的图解法。
On this basis the graphic method of relations among functions of thermodynamics is comprehensively introduced in this paper.
测算和讨论了甘氨酸和吡哆醛结合反应的热力学函数。
The thermodynamic functions of the reaction of glycine with pyridoxal were measured and discussed.
从热力学第二定理出发,利用外微分构造了熵、焓以及吉布斯函数的表达式。
Expressions of entropy, enthalpy and Gibbs function are formulated by exterior differential derived from second law of thermodynamics.
配分函数,也称状态和函数。对于热力学函数的获得及在分布函数的导出中拌演着重要角色。
The partition function, also called the sum over states, It plays an important role in the evaluation of thermodynamic functions and in the derivation of distribution functions.
将循环函数法进行了改进、并应用到实时热力计算中,应用实例表明此种方法概念明确、结果准确、容易在实时计算中实现等特点。
CFM is improved and used for online thermal calculation. The example shows that the method is simple, accurate and can easily be realized in online calculation.
在传统循环函数的基础之上,根据实际热力系统运行的特点,建立了通用加热器数学模型,并对循环函数法进行了改进。
On the base of the original cyclical function method, a general heater model is presented and cyclical function method is improved considering actual operating characteristics of thermodynamic system.
根据铁水预脱硫反应的热力学函数和脱硫反应速率,分析了有利于铁水预脱硫的条件。
Based on thermodynamic function of hot metal predesulphurizing reaction and desulphurizing reaction rate, the conditions beneficial to hot metal predesulphurization was analyzed.
文中三个精确的势能函数可以用实验光谱数据和溶剂化物的热力学数据进行解释。
Three potential functions are explained by using experimental data of spectrum and thermodynamic data of the solvate.
该文就热力学统计物理教材中仲氢分子配分函数的表达式提出了不同看法,并给出了修改建议。
In this article, a different view and suggestion are given about hydrogen molecular partition function in teaching material of the thermodynamics and statistical physics.
本文以理想气体的行为为手段引出熵函数,并以热力学第一定律为基础,论证了熵增大原理。
The state function, entropy, is introduced by the means of a perfect gas behavior, and the second law of thermodynamics is demonstrated based on the first law.
由此可使理想量子气体的热力学函数表示成统一的简洁形式,并进一步揭示了热波长的物理内涵。
It makes the thermodynamic functions of an ideal quantum gas may be expressed in a unified compact form, and the physical connotation of the thermal wavelength is revealed further.
手工方法处理电动势法测热力学函数的实验数据,很难得到满意的结果。
Manual disposal of the experimental data of the thermodynamic function measured with electromotive force can hardly achieve a satisfactory result.
本文从不可逆过程热力学的耗散函数出发,推导了液接电位方程序。
Liquid Junction equation was deduced from the dissipation function of irreversible process thermodynamics.
分析表明过量热力学函数与结合常数K存在较好的相关性。
The relationship between excess thermodynamic function and the binding constant K was suggested.
的热容,熵,升华焓等热力学函数,并与实验值进行了比较。
The standard heat capacity, entropy, sublimation enthalpy of graphite.
利用现行标准的统计力学方法推导出中间统计的巨配分函数,得到了服从中间统计的理想自由粒子模型的热力学函数。
The grand partition function of intermediate statistics with a standard method is derived to calculate the thermodynamic properties of an ideal free-particle model.
利用现行标准的统计力学方法推导出中间统计的巨配分函数,得到了服从中间统计的理想自由粒子模型的热力学函数。
The grand partition function of intermediate statistics with a standard method is derived to calculate the thermodynamic properties of an ideal free-particle model.
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