通过将手性胺和酸基团同时引入到二氧化硅表面制备得到了一种多相双功能催化剂。
A heterogeneous bifunctional catalyst was synthesized by incorporating chiral amine and acid groups into silica.
重点叙述了某些光学活性中间体的工业合成技术,包括手性氨基酸、手性羧酸、手性醇、手性胺和手性环氧化物。
The industrial synthesis of certain optically active intermediates, including chiral amino acids, carboxylic acids, alcohols, amines and epoxides is reviewed.
手性胺化合物广泛存在于自然界中并扮演着重要的角色,亚胺的不对称催化还原反应是制备手性胺化合物的最直接有效的方法。
Chiral amines widely existed and play an important role in the nature. Catalytic asymmetric reduction of imines represents one of the most important methods for preparing chiral amines.
通过磷酰氯与手性仲胺的亲核取代反应高产率地合成了手性HMPA 类似物。
The chiral HMPA analogues were prepared in high yield by nucleophilic substitution between the chiral secondary amine and phosphoryl chloride.
可用于合成各种具芳基胺醇类结构的手性药物。
It can be oriented to produce levo-aromatic and dextro-aromatic alcohols.
通过烯丙基溴化锌对手性亚胺的两次不对称加成,合成了光活性的双烯丙基化的新型手性二胺。
A novel chiral diallylic diamine has been synthesized through double addition of allyl zinc bromide to chiral imines in this contribution.
探索了新型胺类手性衍生试剂-脱氢松香酸酰氯与氨基酸的衍生反应。
We applied dehydroabietyl chloride that is a new chiral reagent for the formation of diastereomers and resolved D, L-amino acid.
手性芳香胺是药物合成的重要中间体,同时也可用作手性助剂及手性拆分剂。
Optically pure arylamines are important building blocks in drug synthesis and are commonly used as chiral auxiliaries and chiral resolving agents.
以磷酰氯为原料通过与手性仲胺的亲核取代反应高产率地合成了手性HMPA类似物。
The chiral HMPA analogues 1 and 2 were prepared in high yield by nucleophilic substitution between the chiral secondary amine and phosphoryl chloride.
综述了手性1,2二苯基1,2 乙二胺及其衍生物的合成,以及作为手性辅助基和手性配体在不对称合成中的应用。
This review summarizes the synthesis and the application of 1,2-diphenyl- 1,2-diaminoethane and its derivatives as chiral auxiliaries, chiral ligands and chiral reagents in asymmetric synthesis.
手性1,2 -二苯基- 1,2 -乙二胺及其衍生物在不对称合成中的应用。
Application of Chiral 1, 2-diphenyl-1, 2-diaminoethane and Its Derivatives in Asymmetric Synthesis.
且可定向提供生成左旋或左旋芳香醇,因此可用于合成各种具芳基胺醇类结构的手性药物的重要中间体。
Furthermore, it can be oriented to produce levo-aromatic and dextro-aromatic alcohols, being an important intermediate to synthesize clural medicines of different arylamino alwhol structures.
且可定向提供生成左旋或左旋芳香醇,因此可用于合成各种具芳基胺醇类结构的手性药物的重要中间体。
Furthermore, it can be oriented to produce levo-aromatic and dextro-aromatic alcohols, being an important intermediate to synthesize clural medicines of different arylamino alwhol structures.
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