氢的替代亲核取代反应(VNS)是与硝基芳环的亲电反应、亲核反应不同的一种新反应。
Vicarious nucleophilic substitution (VNS) of hydrogen is a new type of reaction which is different from the usual electrophilic and nucleophilic reactions of the nitro arenes.
烷基取代的炔丙基硫缩酮衍生物,则能利用相对应的末端炔和碘烷亲电基进行取代反应所获得。
However, alkyl-substituted propargylic dithioacetals could be synthesized by the displacement reaction of the corresponding terminal alkynes with alkyl iodides.
作为亲电体的羰基与作为亲核体的H,C,N和O的羰基化合物反应。
Reactions of Carbonyl Compounds with the Carbonyl Group as an Electrophile with H, C, N and O Nucleophiles.
卤原子作为炔烃三键活化基团和定位基,炔烃三键发生亲电加成反应;
This type of reaction has signicant advantages, the alkyne proceeds the coupling reaction with the halogen atom as the leaving group.
极性转换的本质是有机化合物反应中心碳原子电性发生转换,即亲电性或亲核性发生转换的过程。
The essence of polar conversion is that organic compound reflects the carbon atom electricity in the centre and changes, kiss the electricity or kiss the core course changing.
并且对亲核试剂的体积效应、溶剂效应对亲核性影响,底物上吸电子基团的数目、吸电子能力对亲电性的影响,以及亲核取代反应的发生部位受哪些因素影响进行探讨。
At the same time, discuss about the impact factor to nucleophilicity such as the number of attract electron group, ability of attract electron and the nucleophilic substitution reaction part.
并且对亲核试剂的体积效应、溶剂效应对亲核性影响,底物上吸电子基团的数目、吸电子能力对亲电性的影响,以及亲核取代反应的发生部位受哪些因素影响进行探讨。
At the same time, discuss about the impact factor to nucleophilicity such as the number of attract electron group, ability of attract electron and the nucleophilic substitution reaction part.
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