非常重要的手性源 Chiral Pool
By using chiral metal complexes as catalysts, the optically active products are directly synthesized from the achiral 1, 3-dipolar reagents and achiral alkenes.
而含有手性配体的金属络合物作为催化剂可以直接从非手性的1,3-偶极试剂和烯烃直接合成具有光学活性的产物,为光学活性化合物的合成提供了极大的方便。
参考来源 - TADDOL金属络合物催化硝酮和缺电子烯烃反应的研究·2,447,543篇论文数据，部分数据来源于NoteExpress
研究了重氮烯氢向前手性烯烃单侧的非对映选择性转移。
Diastereoselective transfer of the diazene hydrogen to one face of the prochiral alkene was studied.
目的：研究非负矩阵因子分解算法(NMF)用于手性药物HPLC - DAD二维数据解析的可行性及其影响因素。
Aim: to study the feasibility and influential factors for the resolution of HPLC-DAD data of chiral drugs by non-negative matrix factorization (NMF) algorithm.
手性非天然的芳香族氨基酸是许多药物和天然产物的重要中间体。
Chiral unnatural aromatic amino acids are key intermediates for medicine and natural products.
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