报道在二碘化钐作用下,硫代氨基甲酸酯发生还原反应,得到较好产率的二硫醚和酰胺化合物。
This paper reports reductive reaction of the thiocarbamic esters with samarium diiodide to give disulfidesand carboxamides in good results.
结果表明, 经氯化汞活化的金属钐对酮类化合物与烯丙基或苄基卤代物的反应很有效, 可高产率地生成叔醇。
Samarium metal (activated by HgCl2) is an effective reagent for allylation or benzylation of ketones. The corresponding tertiary alcs. are obtained in satisfactory yields.
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