在有机合成中,芳环化合物的氯甲基化和将苄基卤氧化成芳醛或芳酮是一类极其重要的反应。
In organic synthesis, chloromethylation of aromatic compounds and oxidation of benzylic halides to aromatic aldehydes or aromatic ketones are extremely important reactions.
结果表明, 经氯化汞活化的金属钐对酮类化合物与烯丙基或苄基卤代物的反应很有效, 可高产率地生成叔醇。
Samarium metal (activated by HgCl2) is an effective reagent for allylation or benzylation of ketones. The corresponding tertiary alcs. are obtained in satisfactory yields.
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