在讨论热力学第三定律的时候,我们讨论过压强变化,即对于纯净的完美晶体,随着温度下降到绝对零度熵也变成零。
We looked at pressure change before, actually, in discussing the third law, the fact that the entropy goes to zero as the absolute temperature goes to zero for a pure, perfect crystal.
对零点剩余炳的存在提出了一种新解释,指出零点剩余熵的存在和熵冻结实际上是等价的,比热测量的结果并不违背热力学第三定律。
It is shown that the existence of the residual entropy and the entropy-freezing are in fact equal and that the third law of thermodynamics is still valid in glass systems.
前提是系统要孤立。在热力学行话中,混乱程度叫做熵。第三定律断言,没有一个系统能达到绝对零度。
As long as the system is isolated. In thermodynamics jargon, randomness is called entropy. The third law states that no system can be reduced to 0 K.
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