结果表明,活化势垒太高,反应很难进行,所以单个钯原子不具有催化活性。
The results indicate that a single atom of Pd is unavailable for catalysis owing to its too high activation energy.
提出了一种理论模型以计算原子化的动力学级数和活化能。
A theoretical model has been proposed to calculate the kinetic order and the activation energy for atomization.
卤原子作为炔烃三键活化基团和定位基,炔烃三键发生亲电加成反应;
This type of reaction has signicant advantages, the alkyne proceeds the coupling reaction with the halogen atom as the leaving group.
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