差示扫描量热分析结果表明,当相对分子质量相差不大时,支化度较高的聚乙烯具有较低的熔点。
DSC analysis showed that polyethylene with higher branching degree had lower melting point when relative molecular masses of the polymers were approximate.
茂金属聚乙烯的分子链长支化结构对其流变特性有重要影响,长支链可以使熔体弹性和剪切变稀效应明显增强。
The molecular long chain branch structure of metallocene polyethylene has great effects on it's rheological behavior, long chain branch can significantly enhance melt elasticity and shear thinning.
随着温度的升高聚乙烯产物支化度和甲基支链含量都迅速增加,长支链含量则显著下降。
Branching degree of the polyethylenes and the content of methyl branch rise quickly with reaction temperature, but the content of long branches drops remarkably.
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