单键,在化合物分子中两个原子间以共用一对电子而构成的共价键。通常用一条短线“-”表示。
(E)表示,这里s代表的是单键(single bond )的意思.通常s-顺比s-反稳定,但是二者的转化需要能量,s-反不容易反生diels-alder.
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我们来考虑一下如何划分单键、双键和三键。
Let's think about how we can classify single and double and triple bonds,.
如果来我们看一下单键,让我拿个分子。
So, if we take a look at what a single bond is, and let me grab some molecules here.
每行包含它所属订单的订单键。
OK, then it says draw a single bond from each surrounding atom to the central atom, and subtract two valence electrons.
后将中心原子与其相邻原子之间,连上单键,然后减掉2个价电子。
So if we look at its length, it's actually shorter than a single bond, but longer than a double bond.
因此如果我们看它的键长的话,它实际上比单键更短,却比双键更长。
so you can see that there is going to be two sets in antibonding, three sets in bonding for a net of one, giving us the single bond.
因此你能看到,反键轨道上有两组,三组成键,得到一组净成键,所以成的是单键。
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