在共轭体系中，加成可以发生在共轭体系的两端，也可以发生在其中任何一个双键上。发生在单一双键上的加成称为1，2-加成，而在共轭体系两端发生的加成称为共轭加成（1，4加成或1，6-加成等）。
...配体 不对称催化 共轭加成 烯丙基取代 [gap=524]Keywords】: phosphoramidite ligand,asymmetric catalysis,conjugate addition,allylic substitution ...
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不对称共轭加成 asymmetric addition reaction
In this work, high enantioselectivities were achieved in copper-catalyzed asymmetric tandem conjugate addition-electrophilic fluorination reactions by using chiral BINOL-derived phosphoramidite ligands.3, 3’-Disubstituted BINOL-derived phosphoramidite ligands were prepared from optically pure BINOL.
本文通过对手性联萘单磷配体的改造,成功地实现了铜催化的不对称串联共轭加成-亲电氟化反应。
参考来源 - 催化串联共轭加成—亲电氟化反应—构建手性含氟化合物·2,447,543篇论文数据，部分数据来源于NoteExpress
关键反应为底物控制的不对称杂原子共轭加成反应。
The key step was a substrate controlled asymmetric heteroatom conjugated addition.
铑催化不对称1，4-共轭加成反应是一种非常有效的碳—碳键形成方法。
In this paper, the recent progress in rhodium-catalyzed asymmetric 1,4-conjugate addition reactions is reviewed.
是高度共轭的笼状结构的碳素体，分子结构中六边形环间的共价碳碳双键是富电子区，反应性能与烯烃有类似性，主要表现为双键加成。
C_(60) is one kind of fullerene with high conjugated cage-types structure. Its covalence between two hexagons has high reactivity, which behaves as addition reaction of double bond.
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