含活性基团的醛可与烯丙基碘和锡粉直接进行亲核加成反应,得到高烯丙基型的醇。水的存在不利于此反应的进行。
Aldehyde containing functional groups can react with allyl iodine and tin directly, water is of no advantage to the reaction.
烷基取代的炔丙基硫缩酮衍生物,则能利用相对应的末端炔和碘烷亲电基进行取代反应所获得。
However, alkyl-substituted propargylic dithioacetals could be synthesized by the displacement reaction of the corresponding terminal alkynes with alkyl iodides.
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