例如： 1.3.3 与金属的反应 1.3.3.1 与金属镁的反应 (Grignard reagents) Grignard reagents 中不能包含有下列基团： -OH, -NH2, -NHR, -COOH, -SO3H, -SH, -C ?
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allyl Grignard reagents 烯丙基Grignard试剂
di-grignard reagents 分子双格氏试剂
aryl grignard reagents 芳基格氏试剂
alkynyl grignard reagents 炔基grignard试剂
Grignard Reagents & Alkyl Metals 格氏试剂和烷基金属
However, the carboxide, such as benzaldhyde and methyl chloroacetate can not react with Se Grignard reagent. The possible reason is that the carboxide cause oxidation of Grignard Reagents.
而苯甲醛、氯乙酸甲酯等含羰基化合物可能由于羰基对格氏试剂的氧化反应而不能进行此类反应。
参考来源 - 含硒格氏试剂合成硒醚的研究Grignard reagents are among the most important and traditional organometal reagents. Addition of Grignard reagents to double bonds is one of most reliable methods for forming Carbon-Carbon bonds.
格氏试剂是最重要和最常用的有机金属试剂之一,使用格氏试剂对双键加成是生成碳碳键的重要方法之一。
参考来源 - BINOL·2,447,543篇论文数据，部分数据来源于NoteExpress
It has important meanings in industrialization of Grignard reagents.
这些对格利雅试剂的工业化生产具有重要的意义。
Grignard reagents has a wide range of applications in organic chemistry.
格氏试剂在有机化学中的应用十分广泛。
This paper briefly reviews the research results about small di-Grignard reagents, including their preparation, properties and applications in organic and organometallic synthesis.
介绍了有关小分子双格氏试剂的研究成果，扼要阐述了该试剂的制备、特性以及在有机合成和金属有机合成方面的应用。
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