The experimental results revealed that sulfur atoms in dithiocarbamate coordinated to lanthanides in a didentate manner and an introduction of an ancillary ligand phen to the complexes played an important role in the stabilities of the complexes.
实验结果表明,所有的配合物均呈现镧系离子与配体二硫代甲酸盐相同的配位模式,即镧系离子与配体中的硫原子双齿螯和配位。 辅助配体邻菲哕啉的引入对该类配合物的合成具有重要的稳定作用。
参考来源 - 二硫代甲酸类镧系配合物热解制备倍半硫化物的热过程·2,447,543篇论文数据，部分数据来源于NoteExpress
在镧系离子配合物的水溶液中，镧系离子对配体核的核磁共振弛豫速率具有诱导效应。
The lanthanide ion has the effect of inducing the NMR relaxation rates of the determined nuclei in its coordination compound in aqueous solution.
该传感器以镧系离子(铕离子)作为被检测物质的荧光标记物，根据铕离子的荧光特性，利用时间分辨检测技术进行生物医学检测。
By using lanthanide ions, especially europium ions as the fluorescent labels of samples, TFFBS can perform time resolved fluorescence detection from spectral characteristics of europium ions.
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