Currently asymmetric oxidation ofβ-keto esters is catalyzed by cinchona alkaloids cinchonine in the yield of 68%-85%, ee 44%-50% in large scale.
目前金鸡纳生物碱辛可宁(cinchonine)催化不对称氧化β-酮酸酯化合物(收率68%-85%,ee值44%～50%)已经实现工业化。
参考来源 - 催化β·2,447,543篇论文数据，部分数据来源于NoteExpress
The most efficient way to generate chiral sulfoxides is asymmetric oxidation of prochiral sulfides Catalyzed by chiral metal complexes.
手性金属络合物催化硫醚的不对称氧化是合成手性亚砜最有效的方法。
This review deals with the recent progress in asymmetric synthesis using chiral polymeric reagents and catalysts for oxidation, reduction, alkylation and addition of prochiral compounds.
本文综述了应用手性高分子试剂和催化剂对潜手性化合物通过不对称氧化、还原、烷基化、加成反应进行不对称合成的进展情况。
The turnover-limiting step for the asymmetric allylic oxidation is the formation of chiral catalyst-allyl perbenzoate complexes.
其中催化剂-苯甲酸丁烯酯手性加合物的生成是反应产物的手性决定步骤。
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