以丙酮为溶剂,过氧化氢为氧化剂,考察了环己烷氧化制取环己酮的反应。
The reaction was studied, which used acetone as solvent and hydroperoxide as oxidant to produce cyclohexanone.
以丙酮为溶剂,30%H2O2为氧化剂,两种体系催化苯甲硫醚氧化反应分别可以循环使用两次和三次,但产物亚砜的对映选择性很低。
The two catalytic systems can be recycled twice and three times, respectively, with very low enantioselectivities for the oxidation of phenyl methyl sulfide with 30% H2O2 as oxidant in acetone.
结果表明,升高反应温度、以丙酮为共溶剂或以十二烷基硫酸钠作相转移剂均可使反应速度加快。
The results show that increasing reaction temperature, using acetone as cosolvent or sodium dodecyl sulfate as phase-transfer reagent can accelerate the reaction.
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