当我们讨论多电子原子的轨道时，它们的能量实际上比对应的氢原子轨道要低。
When we talk about orbitals in multi-electron atoms, they're actually lower in energy than the corresponding H atom orbitals.
原子轨道的线性叠加，成分子轨道。
Linear combination of atomic orbitals into molecular orbitals.
这是另外一个1s，氦的原子轨道。
这些轨道起源于，每个原子轨道的组合。
And these orbitals arise from the combination of individual atomic orbital.
说清楚，这是原子氢的1s原子轨道。
This is the 1s. And, just to be clear, this is the 1s atomic orbital in atomic hydrogen.
相比原子轨道它应该更高。
这就是2s原子轨道，这是1s原子轨道。
这种驻波示意图叫做原子轨道。
Standing wave representations such as these are called atomic orbitals.
是因为分子轨道是两个,1s原子轨道的组合。
The 1 s just comes from the fact that the molecular orbital is a combination of two 1 s atomic orbitals.
这是原子轨道。
我们应该把反键轨道标在，高于1s原子轨道能量的地方。
So we would label our anti-bonding orbital higher in energy than our 1 s atomic orbitals.
你们发现当你有个成键轨道的时候，相比原子轨道能量要降低。
And what you find is when you have a bonding orbital, the energy decreases compared to the atomic orbitals.
同样的，我们可以填充原子轨道，每个原子轨道上有两个电子。
So again, we can fill in our atomic orbitals here, there's going to be two electrons in each of our atomic orbitals.
如果我们看分子轨道的话，它实际上要比，两个原子轨道都要低。
So, if we look at the molecular orbital, that's actually going to be lower in energy than either of the two atomic orbitals.
我希望你们能确保，你们笔记上氢原子轨道图是完整的。
So I wanted to make sure you have a complete set for hydrogen in your notes.
我们可以相长，和相消叠加这些波，这些原子轨道可以杂化。
So we can actually constructively and destructively combine these waves, these atomic orbitals to make a hybrid.
提出了用数轴判断中心原子轨道杂化方式的方法、应用及规律。
This paper gives a method of judging the hybridization form of central atomic orbital by number axis, its applications and laws.
这证明了，反键轨道，比原子轨道高，成键轨道比原子轨道第。
It turns out that the antibonding orbital is a little bit higher from the atomic orbital level than the bonding orbital is lower.
本文提出了由赝原子轨道组成的集团计算半导体中深能级的方法。
A method based on a cluster model composed by pseudo-atomic orbitals is proposed for the calculation of deep energy levels in semiconductors.
当我们填充轨道的时候可以看到，我们用的是和，填充原子轨道一样的原则。
So again you can see as we're filling up our molecular orbitals, we're using the exact same principle we used to fill up atomic orbitals.
本文从氢的复函原子轨道出发，构造了氢分子的两类零级波函数集。
In this paper, two type of wave function of zeroth degree for hydrogen molecule are constructed, starting from atomic orbitals of hydrogen in complex form.
当我们比较原子轨道和分子轨道的时候，我们来考虑一下相互作用能。
So, let's think of the energy of interaction when we're comparing atomic orbitals to molecular bonding orbitals.
分子轨道对于单个原子轨道来说，我们可以看到的是一个净的能量降低。
What we've seen is we have a net lowering of energy of the molecule versus the individual atoms.
在多电子原子和氢原子，之间还有一个区别，当我们谈论多电子原子轨道时。
And there again is another difference between multi-electron atom and the hydrogen atoms.
我们先来看一看相长干涉，另外一个解释它的方法就是说，分子轨道是原子轨道的组合。
So, we'll start by taking a look at constructive interference, and another way to explain this is just to say again, molecular orbitals are a linear combination of atomic orbitals.
通过数据还发现氰戊菊酯中的三个苯环的原子轨道间也存在较强的相互作用。
It is also revealed that there are fairly strong interactions among the atomic orbitals of the three phenyl of fenvalerate.
我准备将原子轨道组合起来，进行分子轨道计算，这个过程还需添加一些系数。
I am going to sum up the atomic orbitals that go into the molecular orbital, and they are going to have some coefficients.
提出了由分子的“不饱和度”判断中心原子轨道杂化方式的方法、应用及规律。
This paper gives the method of judging the hybridization form of central atomic orbital by unsaturation, applications and its laws.
因此，研究者们绘制了在下面的原子轨道的结点结构，从根本上说是画出了含有电子的空间轮廓。
Thus, the researchers mapped the "nodal structure" of the underlying molecule's orbital, essentially sketching an outline of the Spaces that contained electrons.
量化计算所得原子轨道贡献和原子净电荷布居分析结果与晶体结构中的配位情况相符。
The orbital contribution and atomic net charge results had provided a good testimony for the coordinated condition in the crystal structure.
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