可以使用氢化物离子亲和力评估碳正离子和碳负离子的稳定性。
Carbocation and carbanion stabilities can be assessed using hydride ion affinities.
另一种是通过碳正离子中间体进行的,它所得到的产物无立体选择性。
The other is conducted amidst carbonium ion intermediate and the product thus brought about has no stereoselectivity.
本文用热力学和碳正离子化学的观点,对同碳二元醇的稳定性进行了讨论。
The Stability of gem-diols is discussed and interpreted in this paper in terms of thermodynamics and Carbanium Chcmistry.
其结果证实:在种种分子重排反应中,总是趋向于生成结构更稳定的碳正离子或碳负离子或自由基中间体及其产物。
Their result affirm: in all sorts of molecular rearrangement reactions, anyway tend to produce more stable carbocation, or carboanion, or free radical middle substance and their products.
作者认为高配位数碳化合物体系这种在一定条件下多配位数的普遍性,也应当有助于认识争论中的所谓“非经典碳正离子问题。”
The author considers that the generality of higher-coordinating ability of hypercoordinate carbon compounds under certain conditions will be helpful to the understanding of the socalled "no…"
作者认为高配位数碳化合物体系这种在一定条件下多配位数的普遍性,也应当有助于认识争论中的所谓“非经典碳正离子问题。”
The author considers that the generality of higher-coordinating ability of hypercoordinate carbon compounds under certain conditions will be helpful to the understanding of the socalled "no…"
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