• Since we're talking about wave functions, since we're talking about the properties of waves, we don't only have constructive interference, we can also imagine a case where we would have destructive interference.

    因为我们讨论的是函数,因为我们讨论的是的性质,我们不仅有长干涉,我们也可以想象在,某种情况下会有消干涉。

    麻省理工公开课 - 化学原理课程节选

  • And all we mean by constructive interference is that literally those two waves add together, such as the maxima are now twice as high, and the minima are now twice as low.

    长,长也就是,说两个加在一起,所以最大值变成2倍那么高,最低值变成2倍那么低。

    麻省理工公开课 - 化学原理课程节选

  • Ever since this was first proposed, there has never been any observations that do not coincide with the idea, that did not match the fact that the probability density is equal to the wave function squared.

    从未有,任何观测,与它抵触,从没有过,函数的平方不等于,概率密度的情况,关于马克思,恩。

    麻省理工公开课 - 化学原理课程节选

  • So we can actually constructively and destructively combine these waves, these atomic orbitals to make a hybrid.

    我们可以长,和消叠加这些,这些原子轨道可以杂化。

    麻省理工公开课 - 化学原理课程节选

  • And in either case if we first talk about constructive interference, what again we're going to see is that where these two orbitals come together, we're going to see increased wave function in that area, so we saw constructive interference.

    在任何情况下,如果我们首先讨论长干涉的话,我们同样会看到,当这两个轨道靠拢的时候,我们看到这个区域有函数增加,所以我们看到的是长干涉。

    麻省理工公开课 - 化学原理课程节选

  • The reason that we can talk about this is remember that we're talking about wave functions, we're talking about waves, so we can have constructive interference in which two different orbitals can constructively interfere, we can also have destructive interference.

    我们可以这么说的原因是,记住我们说的是函数,我们说的是函数,所以我们可以得到长干涉,这是两个不同轨道会长干涉,我们也有消干涉。

    麻省理工公开课 - 化学原理课程节选

  • But first, I just want to remind you when we're talking about molecular orbital theory, this is treating electrons as waves, so what we're actually able to do is either constructively or destructively combine atomic orbitals to form molecular orbitals.

    但首先,我要提醒你们,当我们讨论,分子轨道理论的时候,我们把电子看作是一种,所以我们可以长叠加,或者消叠加这些原子轨道来组成分子轨道。

    麻省理工公开课 - 化学原理课程节选

  • So we can draw that for 1 s a, we can also draw it for 1 s b, and what I'm saying for the molecular wave function is that we have the interference between the two, and we have a constructive interference, so we end up adding these two wave functions together.

    所以我们可以对1sa画出它来,我们也可以对1sb画出它来,对于分子函数我要说的是,它们两者之间会干涉,这里我们有长干涉,所以我们得到的是两个函数加起来。

    麻省理工公开课 - 化学原理课程节选

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