This should be particularly bothersome to you because, as you've already experienced in 5.60, There are a lot of partial derivatives.
对你们来说这可能很让人头疼,就像你们在5。60里体验过的那样,这有很多偏微分和变量。
When you say that, it implies that the differential is given by this pair of partial derivatives.
这就意味着,内能的微分,等于偏u偏T,保持体积不变。
We have discovered that this partial derivative that appears in the definition, the abstract definition of the differential for internal energy, is just equal to the constant volume heat capacity.
我们还发现,这个偏微分出现在了,内能的偏微分,定义式中,它也就是热容。
So, using those, now, what happens if we take the second derivative of A, the mixed derivative, partial with respect to T and the partial with respect to V.
如果我取A的二阶导数,混合导数,对T偏微分,再对V偏微分。
So we already know that. So now we can write CpdT or differential dH as Cp dT plus dH/dp, pdp constant temperature, dp.
我们已经知道了这个,所以我们现在,可以写出H的微分式:dH等于,加上恒温时的偏H偏。
du/dT constant pressure is the direct derivative with respect to temperature here, which is sitting by itself under constant volume keeping this constant but there is temperature sitting right here too.
偏U偏T,p恒定是对,温度的直接微分,而它本身对体积不变,保持它不变,但是这里也有一个温度,这就是偏U偏V,T恒定。
应用推荐