• So again, if we think about that shape of that carbon atom, it's going to be trigonal planar, 120° it's going to have bond angles of 120 degrees, because we have this set up of having three hybrid orbitals.

    如果我们考虑碳原子的形状,它是平面三角形,键角是,因为我们有这三个杂化轨道

    麻省理工公开课 - 化学原理课程节选

  • So, if we say that in this entire plane we have zero probability of finding a p electron anywhere in the plane, the plane goes directly through the nucleus in every case but a p orbital, so what we can also say is that there is zero probability of finding a p electron at the nucleus.

    而只要是p轨道,这个平面都直接,穿过原子核,那么我们,可以说在原子核上,找到一个p电子的概率为零。

    麻省理工公开课 - 化学原理课程节选

  • But in sigma orbitals, you have no nodal planes along the bond axis, so if we had a nodal plane here, we'd see an area where the wave function was equal to zero.

    但在sigma轨道里,沿着轴向是没有节点平面的,如果我们有个节点,我们就会看到某个地方波函数等于0。

    麻省理工公开课 - 化学原理课程节选

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