• Our friend Schr?dinger told us that if you solve for the wave function, this is what the probability densities look like.

    我们的朋友薛定谔告诉我们,如果你用函数来解决,你就会知道这些概率密度看上去的样子。

    麻省理工公开课 - 固态化学导论课程节选

  • We can talk about the wave function squared, the probability density, or we can talk about the radial probability distribution.

    我们可以讨论它,函数的平方,概率密度,或者可以考虑它的径向概率分布。

    麻省理工公开课 - 化学原理课程节选

  • But we can also think when we're talking about wave function squared, what we're really talking about is the probability density, right, the probability in some volume.

    函数平方,的时候,我们说的,是概率密度,对吧,是在某些体积内的概率,但我们有办法。

    麻省理工公开课 - 化学原理课程节选

  • Ever since this was first proposed, there has never been any observations that do not coincide with the idea, that did not match the fact that the probability density is equal to the wave function squared.

    从未有,任何观测,与它相抵触,从没有过,函数的平方不等于,概率密度的情况,关于马克思,恩。

    麻省理工公开课 - 化学原理课程节选

  • Similarly, if we were to look at the radial probability distributions, what we would find is that there's an identical nodal structure.

    相似地如果我们看看,径向概率分布,我们会发现有一个完全相同的节结构。

    麻省理工公开课 - 化学原理课程节选

  • So again if we look at this in terms of its physical interpretation or probability density, what we need to do is square the wave function.

    如果我们从物理意义或者,概率密度的角度来看这个问题,我们需要把函数平方。

    麻省理工公开课 - 化学原理课程节选

  • So, that's probability density, but in terms of thinking about it in terms of actual solutions to the wave function, let's take a little bit of a step back here.

    这就是概率密度,但作为,把它当成是,函数的解,让我们先倒回来一点。

    麻省理工公开课 - 化学原理课程节选

  • So, we can look at other radial probability distributions of other wave functions that we talked about.

    我们可以来看一看我们讨论过的,其它一些函数的径向概率分布。

    麻省理工公开课 - 化学原理课程节选

  • So, at this place where it hits zero, 0 that means that the square of the wave function is also going to be zero, right.

    它达到0的地方,这意味着函数的,平方也是,如果我们看概率密度图。

    麻省理工公开课 - 化学原理课程节选

  • So again, we can think about the probability density in terms of squaring the wave function.

    同样的,我们可以把,函数平方考虑概率密度。

    麻省理工公开课 - 化学原理课程节选

  • So the probability again, that's just the orbital squared, the wave function squared.

    同样,概率密度,这就是轨道的平方,函数的平方。

    麻省理工公开课 - 化学原理课程节选

  • So if we're talking about probability density that's the wave function squared.

    如果我们要讨论概率密度,这是函数的平方。

    麻省理工公开课 - 化学原理课程节选

  • That should make sense to us, because when we talk about a wave function, we're talking about a probability divided by a volume, because we're talking about a probability density.

    因为我们说,函数,是概率,除以体积,因为我们说的是,概率密度,如果我们用它。

    麻省理工公开课 - 化学原理课程节选

  • So, what we can do to actually get a probability instead of a probability density that we're talking about is to take the wave function squared, which we know is probability density, and multiply it by the volume of that very, very thin spherical shell that we're talking about at distance r.

    我们能得到一个概率,而不是概率密度的方法,就是取函数的平方,也就是概率密度,然后把它乘以一个在r处的,非常非常小的,壳层体积。

    麻省理工公开课 - 化学原理课程节选

  • I have yet to show you the solution to a wave function for the hydrogen atom, so let me do that here, and then we'll build back up to probability densities, and it turns out that if we're talking about any wave function, we can actually break it up into two components, which are called the radial wave function and angular wave function.

    我还没有给你们看过,氢原子函数的解,让我现在给你们看一下,然后再来说,概率密度,实际上,对于任何一个函数来说,我们可以把它,分解为两部分,分别叫做径向函数,和角向函数。

    麻省理工公开课 - 化学原理课程节选

  • So, we can do that by using this equation, which is for s orbitals is going to be equal to dr 4 pi r squared times the wave function squared, d r.

    用这个方程,对于s轨道,径向概率分布,4πr的平方,乘以函数的平方,这很容易理解。

    麻省理工公开课 - 化学原理课程节选

  • You can also have angular notes, and when we talk about an anglar node, what we're talking about is values of theta or values of phi at which the wave function, and therefore, the wave function squared, or the probability density are going to be equal to zero.

    我们也可以有角向节点,当我们说道一个角向节点时,我们指的是在某个theta的值,或者phi的值的地方,函数以及函数的平方,或者概率密度等于零。

    麻省理工公开课 - 化学原理课程节选

  • And what here is just a graph of the 1 s wave function going across some radius defined this way, and you can see that the probability - well, this is the wave function, so we would have to square it and think about the probability.

    这里是,1s函数,沿这个方向的图,你们可以看到概率,这是函数,所以我们可以把它平方,并想成是概率

    麻省理工公开课 - 化学原理课程节选

  • We call that a node, r and a node, more specifically, is any value of either r, the radius, or the two angles for 0 which the wave function, and that also means the wave function 0 squared or the probability density, is going to be equal to zero.

    节点就是指对,于任何半径,或者,两个角度,函数等于,这也意味着函数的平方或者概率密度,等于,我们可以看到在1s轨道里。

    麻省理工公开课 - 化学原理课程节选

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