• I can then subsequently lose an electron from the lithium ion. Lithium ion loses an electron to become lithium 2plus.

    然后我能在锂离子中,失去一个电子,锂离子失去一个电子,变为二价锂离子。

    麻省理工公开课 - 固态化学导论课程节选

  • And, likewise, if we look at fluorine in its diatomic molecule, it is 160 kilojoules per mole.

    一样的,如果我们观察二价的氟,它是每摩尔160焦。

    麻省理工公开课 - 固态化学导论课程节选

  • So, selenium 2 minus is what's going to be isoelectronic, because if you add two electrons to selenium, you'll get the same electron configuration that you have for krypton here.

    二价的硒离子将是等电子的,因为如果你给硒原子加上两个电子,你会得到,和氪原子相同的电子排布。

    麻省理工公开课 - 化学原理课程节选

  • And you would expect that that would be a much stabler compound because, instead of plus one attracting plus one, now you have plus two attracting minus two.

    可以预见,这将会是更稳定的化合物,因为不再是一正离子吸引一负离子,而是二价正离子吸引二价负离子。

    麻省理工公开课 - 固态化学导论课程节选

  • It's 109 . 5 is what we would expect for methane because it's tetravalent, but here we're just seeing something that's divalent, and they're both in p orbitals that are perpendicular to each other.

    因为甲烷是四的,我们预测是109。,但这里我们,看到的是二价的,它们都在。

    麻省理工公开课 - 化学原理课程节选

  • Because aluminum ions have charge of plus three and oxygen ions have charge of minus two.

    因为铝离子为正三,氧为负二价

    麻省理工公开课 - 固态化学导论课程节选

  • So this should immediately look like a problem because we know, in fact, that methane is tetravalent, and this is telling us it's only divalent.

    显然这看起来是一个问题,因为我们知道实际上,甲烷是四的,而这告诉我们它仅仅是二价的。

    麻省理工公开课 - 化学原理课程节选

  • So, we can say that -- if we have neon here and we want to think about what's isoelectronic, -- f minus would be isoelectronic. We also have oxygen -- what would the charge on oxygen be? Um-hmm, right. 2 minus.

    那么,我们可以说--如果我们这里有氖原子,而我们想知道与它等电子的是什么,负一的氟离子就是与它等电子的,我们还有氧-,氧应该是几的?没错,负二价

    麻省理工公开课 - 化学原理课程节选

  • And then a lithium 2plus still has an electron.

    然后二价锂离子仍有一个电子。

    麻省理工公开课 - 固态化学导论课程节选

  • What about lithium 2+?

    那么二价的锂呢?

    麻省理工公开课 - 固态化学导论课程节选

  • So, what we call this is the third ionization energy, or the negative of the binding energy, again of the 2 s orbital, but now it's in boron plus 2 to we're starting with.

    那么我们称它为第三电离能,或者负的束缚能,还是,2,s,轨道的,但现在我们是从正二价硼离子开始的。

    麻省理工公开课 - 化学原理课程节选

  • The highest occupied orbital is now the 2 s orbital, 1 s 2 2 s 1 so we're going to end up with boron 2 plus 1 s 2, 2 s 1, plus the electron coming out of there.

    现在最高的被占据轨道是,2,s,轨道,因此结果应该是正二价的硼,再加上一个出射的电子。

    麻省理工公开课 - 化学原理课程节选

  • And what I want to point out that we just figured out for molecular orbital theory, is that o 2 is a biradical, because remember, the definition of a radical is when we have an unpaired electron.

    我要指出的是,我们刚利用分子轨道理论,指导了O2是二价自由基,因为记住,自由基的定义是,有个未配对的电子。

    麻省理工公开课 - 化学原理课程节选

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