• So we have the operationon the wave function in terms of r, theta, and phi and remember this e is just our binding energy for the electron, and we get back out this wave function.

    我们用r,θ,φ来表示,将算符作用于波函数,而且记住e仅仅是电子结合能,然后后面加上波函数。

    麻省理工公开课 - 化学原理课程节选

  • You can also have angular notes, and when we talk about an anglar node, what we're talking about is values of theta or values of phi at which the wave function, and therefore, the wave function squared, or the probability density are going to be equal to zero.

    我们也可以有角向节点,当我们说道一个角向节点时,我们指的是在某个theta的值,或者phi的值的地方,波函数以及波函数的平方,或者概率密度等于零。

    麻省理工公开课 - 化学原理课程节选

  • In contrast when we're looking at a p orbital, so any time l is equal to 1, and you look at angular part of the wave function here, what you see is the wave function either depends on theta or is dependent on both theta and phi.

    相反当我们看p轨道时,任何时候l等于1,你们看它的角向波函数,你们可以看到它要么是和theta有关,要么是和theta和phi都有关。

    麻省理工公开课 - 化学原理课程节选

  • l But now we need to talk about l and m as well. So now when we talk about a ground state in terms of wave function, we need to talk about the wave function of 1, 0, 0, and again, as a function of r, theta and phi.

    但我们现在需要讨论,和m,现在当我们讨论,波函数的基态时,我们讨论的,是1,0,0的波函数,同样的,它也是r,theta和phi的函数。

    麻省理工公开课 - 化学原理课程节选

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