• If these bonds were all completely of equal distance apart, whether is was a lone pair or bonding electrons, 5° the angles would be 109 . 5 degrees.

    如果不管它是孤对,还是成键,它们等距分开的话,键角是109。

    麻省理工公开课 - 化学原理课程节选

  • Yeah, so also 4. We started with 10 valence electrons, we used up 6 of those as bonding electrons, so we have 4 left, which will be lone pair electrons.

    对,也是四个,我们从十个价电子开始,只用了六个来成键,因此我们还剩下四个,它们将成为孤对电子。

    麻省理工公开课 - 化学原理课程节选

  • That's because you have to satisfy this base pair matching in order to have hydrogen bonding in each of the struts of the ladder in order to form a stable structure.

    NA双链要满足互补配对原则,以使碱基对之间,形成氢键,从而形成稳定的双链结构

    耶鲁公开课 - 生物医学工程探索课程节选

  • So if we take a look at nitrogen here, what you'll notice is we have thre available for bonding, - and we already have our lone pair -- one of our orbitals is already filled up.

    如果我们看一下氮原子,我们注意到我们可以成3个键,我们已经有一个孤对-,其中的一个轨道已经被填满了。

    麻省理工公开课 - 化学原理课程节选

  • For the sulfur, we start off with 6 valence electrons, minus 4 lone pair electrons, minus 2, taking in account our bonding electrons, so we end up with a formal charge of 0.

    对于硫,我们从六个价电子开始,减去四个孤对电子,再减去二,算上我们的成键电子,因此最终我们有零个形式电荷。

    麻省理工公开课 - 化学原理课程节选

  • That's what we call when we have three bonding atoms and one lone pair.

    这是当我们有3个成键电子,和一个孤对时这样称它。

    麻省理工公开课 - 化学原理课程节选

  • So what we see is on ammonia here, 107 we know that it's less than a 109 . 5, it's actually 107, so it's less than a 109 . 5, because of that lone pair pushing down in the bonding electrons.

    我们看到在氨分子里,我们知道它比109.5要小,它是,所以比109。5要小,因为孤对会把成键电子向下推。

    麻省理工公开课 - 化学原理课程节选

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