They are a function of the instant atomic arrangement, how we arrange the atoms: same composition, simple example, one inch thick pine board, one inch thick plywood.
那是即时的原子排序,的功能,我们如何排序原子,同样的成分,简单的例子,一英寸厚的松木板,一英寸厚的胶合板。
One is a little bit higher and one is a little bit lower than they are in the atomic situation.
一个有点高,一个有点低,相比他们是原子状态的情景而言。
So would you expect, therefore, as we go across a row for the atomic radius, to increase or to decrease? Good. OK, yes.
那么大家觉得,原子半径沿着某一行向右走,是会增大还是会减小呢?很好,不错,是的。
And so, for today, for example, it says Classification Schemes, Mendeleev, Atomic Structure, A Readings Chapter 1, Chapter 2, Appendix A.
今天,举个例子,讲的是分类法,门捷列夫,原子结构,阅读第1,第2章,和附录。
And the technique is called, watch because this is a six-letter initialization, linear combination of atomic orbitals LCAO-MO into molecular orbital, LCAO-MO.
这项技术是,一个6字母初始设定,原子轨道的线性叠加,成分子轨道。
Mendeleev is the one who taught us that the properties of the elements are a function of the atomic mass.
门捷列夫教授我们元素特性,是元素质量所起的功能。
It turns out that the antibonding orbital is a little bit higher from the atomic orbital level than the bonding orbital is lower.
这证明了,反键轨道,比原子轨道高,成键轨道比原子轨道第。
And what you find is when you have a bonding orbital, the energy decreases compared to the atomic orbitals.
你们发现当你有个成键轨道的时候,相比原子轨道能量要降低。
He had a tube with electrodes potted in it filled with atomic hydrogen. And by applying a voltage, he was able to get the gas to glow.
那是个装满了氢原子并含有电极的管子,通过增加一个电压,他让气体燃烧起来了。
We'll then take a turn to talking about the periodic table, we'll look at a bunch of periodic trends, including ionization energy, electron affinity, electronegativity and atomic radius.
然后我们再开始讲元素周期表,我们会看到很多周期性规律,比如电离能,电子亲和能,电负性以及原子半径。
You can see the atomic mass unit will be, excuse me. Let me go at it a different way.
你可以看到原子质量单位就是,不好意思,我们换个方式说。
We have a table of the elements with properties varying periodically with atomic mass, so we compress all of that information and refer to it as the Periodic Table.
我们有一个元素表,其中的元素的特性,随着原子质量的改变而引起周期性的变化,所以我们将所有的信息精简,将它变成一个周期表。
We talked about ionization energy, electron affinity, we talked about electronegativity, which is just kind of a combination of the first two, and then ended with atomic radius here.
我们讲了电离能的,电子亲和能的,还讲了电负性的,也就是前两个的组合,最后讲了原子半径的。
So, we'll start by taking a look at constructive interference, and another way to explain this is just to say again, molecular orbitals are a linear combination of atomic orbitals.
我们先来看一看相长干涉,另外一个解释它的方法就是说,分子轨道是原子轨道的组合。
We are expecting to see that it decreases because it's feeling a stronger pull, all the electrons are being pulled in closer to the nucleus, so that atomic size is going to get smaller.
我们将看到它是减小的,因为电子会感受到越来越强的吸引力,所有的电子将会被原子核拉得越来越近,所以原子半径将越来越小。
s1 Here is 1s atomic. But lithium has 2s1, so I need a 2s atomic orbital here and likewise over here.
这是1s原子,但锂有两层,所以我还需要在这里添加2s轨道,就像那样。
There was a lot of physics going on, but we didn't know a whole lot about atomic structure back in those days.
物理学在迅速发展,但在这之前并没有人对,原子结构有很全面的了解。
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