• "But the size and configuration of this facility is inconsistent with a peaceful program."

    VOA: standard.2009.09.25

  • The electronic configuration, all it is is the shorthand notation for that one electron approximation for the Schrodinger equation for lithium.

    电子构型就是,对于锂的薛定谔方程,的单电子近似的,简化形式。

    麻省理工公开课 - 化学原理课程节选

  • So let's figure out the bond order for our two molecules here that we figured out the electron configuration for.

    让我们看看这里,两个分子的键序是多少。

    麻省理工公开课 - 化学原理课程节选

  • And we talked about a triad being a configuration of three pitches where you take the first, the third and the fifth.

    三和弦是由三个音高配置成的,你们可选取第一,第三和第五个音。

    耶鲁公开课 - 聆听音乐课程节选

  • Milton's pushing here toward a fantasy of physical invulnerability imagining an alternative -- this is science fiction an alternative model of bodily configuration that would render impossible the all-too-easy quenching of the tender eyeballs.

    弥尔顿在这幻想着人的身体可以刀枪不入,他在想象一个另类的-这只是科幻,他在想象一个另类的身体构造模型,这样脆弱的眼球,就不会轻易受到伤害。

    耶鲁公开课 - 弥尔顿课程节选

  • So here's the pneumonic I mentioned for writing the electron configuration and getting those orbital energies in the right order.

    这里是我提到的,对于写电子构型,和以正确的顺序得到轨道能量。

    麻省理工公开课 - 化学原理课程节选

  • So it looks like most of you got that the electron configuration that we're writing here is for copper.

    看来大多数人,都看出了,这是铜原子的电子排布。

    麻省理工公开课 - 化学原理课程节选

  • So if we think about what we would do to actually write out this configuration, we just write the energy levels that we see here or the orbital approximations.

    如果我们考虑我们所做的去,实际写出电子构型,我们只是写出我们看到的能级,或者是轨道近似就可以了。

    麻省理工公开课 - 化学原理课程节选

  • And the reason that we use it is that it is incredibly accurate, and allows us to very, very quickly predict and to predict accurately, in most cases, what the electron configuration of molecules are going to be.

    我们用它是因为它极为精确,并且能让我们非常非常快地预测,而且是准确地预测,大多数情况下,分子应该具有的电子排布。

    麻省理工公开课 - 化学原理课程节选

  • But, of course, what you saw in recitation, and hopefully, what you can now think very quickly by looking at this, is that this is not the only configuration of pi bonds that we could have in benzene.

    当然,你们在习题课看到过,你们通过看这个可以很快的想到,这不是苯环里,唯一的π键构型。

    麻省理工公开课 - 化学原理课程节选

  • And this is the same periodic table that you're going to get in your exams, so it's good to practice doing your problem-sets with that periodic table so you're not relying on having the double check right there of seeing what the electron configuration is.

    这也是你们考试时会用到的相同的表,这样你们就不会,所以使用周期表来做问题集,是很好的练习,这样你们就,不会依赖于再次确认,电子构型是什么了。

    麻省理工公开课 - 化学原理课程节选

  • Then something that you probably have a lot of experience with is talking about electron configuration and writing out the electron configuration.

    然后有一些事情是,你们可能有较多经验,那就是讨论电子构型以及,写出它们。

    麻省理工公开课 - 化学原理课程节选

  • These are all isoelectronic, they all have the same electron configuration. And we can also think about going back to atomic size for a second.

    这些都是等电子的,它们都有相同的电子排布,而,我们还可以再回想一下原子尺寸的概念。

    麻省理工公开课 - 化学原理课程节选

  • And again, I've written for you, but you can figure out what the electron configuration is just by writing up in this order here.

    同样,我已经写出来了,但你们可以把这个写出来,就知道电子轨道构型是什么。

    麻省理工公开课 - 化学原理课程节选

  • So, as an example, let's take argon, I've written up the electron configuration here, and let's think about what some of the similarities might be between wave functions in argon and wave functions for hydrogen.

    所以作为一个例子我们来看看氩,我已经把它的电子构型写在这里,我们来考虑氩和,氢波函数之间的,一些相似性。

    麻省理工公开课 - 化学原理课程节选

  • So for example, if we think about fluorine, 1 s 2 2 s 2 2 p 5 that has an electron configuration of 1 s 2, 2 s 2, 2 p 5, so all we would need to do is add one more electron to get the same configuration as for neon.

    比如,如果我们考虑氟原子的话,它的电子排布是,因此我们所需要做的就是给它加上一个电子,使得它与氖原子的电子排布相同。

    麻省理工公开课 - 化学原理课程节选

  • So basically, at the time he was just going on size and then traits, but what we actually know today is that we can also order things in the periodic table by electron configuration.

    基本上,在当时他只能通过大小,和特性来进行,但是现在我们已经知道了,我们还可以通过电子排布来对它们进行排序。

    麻省理工公开课 - 化学原理课程节选

  • So, in this one we're selecting the correct electronic configuration for an ion.

    那么,这次我们要做的是,选出一个离子正确的电子排布。

    麻省理工公开课 - 化学原理课程节选

  • So here we're talking about v plus 1, so if we were to write it just for the neutral electron itself, we would find that the electron configuration is argon, that's the filled shell in front of it.

    这里我们要分析的是正一价的钒离子,因此,我们先写出中性原子的电子排布,可以发现,其原子实是氩原子的电子排布,这些壳层已经被占满了。

    麻省理工公开课 - 化学原理课程节选

  • God's extremely peculiar configuration of the human body You read this and you realize that Samson is really on to something here Why didn't, we ask with Samson God implant the sense of sight in human beings just as he implanted the sense of touch or feeling?

    还有上帝对人体极其古怪的构造,读这些你们就能意识到参孙在这确实知道一些意图,我们和参孙一样也想问,为什么上帝不让人类拥有视觉,就像让人类当初拥有触觉一样?

    耶鲁公开课 - 弥尔顿课程节选

  • So, selenium 2 minus is what's going to be isoelectronic, because if you add two electrons to selenium, you'll get the same electron configuration that you have for krypton here.

    负二价的硒离子将是等电子的,因为如果你给硒原子加上两个电子,你会得到,和氪原子相同的电子排布。

    麻省理工公开课 - 化学原理课程节选

  • So let's do this considering, for example, what it would look like if we were to write out the electron configuration for oxygen where z is going to be equal to 8.

    我们来做这个考虑,举例来说,如果我们写出,有效电荷量为8的氧的电子构型。

    麻省理工公开课 - 化学原理课程节选

  • So, if we want to think about what the first ionization energy is of boron, what you want to do is write out the electron configuration, because then you can think about where it is that the electron's coming out of.

    如果我们要考虑,硼的第一电离能,你首先要做的是写出它的电子排布,因为在这之后,你才能知道拿走的是哪里的电子。

    麻省理工公开课 - 化学原理课程节选

  • And I know there's a lot to talk about this competition, but let's just get into listening mode here and talk about how we can figure out what the correct electron configuration is for this ion.

    我知道刚才关于这次比赛大家有很多话要聊,但是请大家先转换到听讲的模式,来看看如何才能弄清楚,这个离子正确的电子排布。

    麻省理工公开课 - 化学原理课程节选

  • The first thing we need to do is write the electron configuration for the atom itself, and then we need to take an electron away.

    首先我们要做的是,写出原子的电子排布,然后,我们再拿走一个电子。

    麻省理工公开课 - 化学原理课程节选

  • So let's think about what the valence electron configuration is here.

    让我们看看这里的,电子构型是什么样的。

    麻省理工公开课 - 化学原理课程节选

  • In the first case, so here is the electron configuration of neon.

    首先,这是氖原子的电子排布。

    麻省理工公开课 - 化学原理课程节选

  • Let's move on to the last topic in terms of this first exam, which is thinking about the idea of isoelectronic atoms, or isoelectronic ions. And isoelectronic is very straightforward, it just means having the same electron configuration.

    下面我们继续讲第一次考试的最后一个主题,也就是等电子原子,或等电子离子的概念,“等电子的“是非常直接的表达,它的意思就是具有相同电子排布的。

    麻省理工公开课 - 化学原理课程节选

  • So, Lewis structures are really a model for a way to think about what the valence electron configuration is, and as I said, it's not based on quantum mechanics, it's something that Lewis observed far, far before quantum mechanics were discovered.

    路易斯结构实际上是一个用来考虑价,电子排布的模型,而就像我说的,它并不以量子力学为基础,而是路易斯在以前发现的,在量子力学出现很早前。

    麻省理工公开课 - 化学原理课程节选

  • And resonance is the idea that sometimes one single Lewis structure does not adequately describe the electron configuration around a given molecule, so instead you need to draw two different Lewis structures to describe that more appropriately.

    而所谓共振态,就是有时候一个路易斯结构不足以,完整描述一个给定分子的电子排布,因此这时你需要同时画出两个,不同的路易斯结构来描述它,这样会更恰当。

    麻省理工公开课 - 化学原理课程节选

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