It's much more relevant to set our zero point energy as the separation of a bond in terms of talking about the reactions that we'll usually be dealing with here.

更好的是把零点能定在,键断裂的时刻,在讨论化学反应的时候,而我们以后将经常遇到化学反应。

麻省理工公开课 - 化学原理课程节选

And so what I get is the energy of the system at the equilibrium separation is given by minus z plus.

这就是通过减去z+得到得平衡分离时,我得到的能量体系。

麻省理工公开课 - 固态化学导论课程节选

Often a good thing to start with is to put the lowest ionization energy atom in the middle, and if you don't have charge separation then go with that structure, but if you do find you have a lot of separation, such as the case in negative 2, positive 2, and minus 1, then you want to say wait a second, this is really bad in terms of formal charge, let me go ahead and see what other options I have here.

通常一开始把电离能最低的原子,放在中心位置就很好了，如果你发现电荷没有分开,那么这个结构就没问题了，但是如果你发现有很多分开的电荷，比如这种情况，有负二，正二和负一，那么你会想要说等一下，从形式电荷来看这很不好，让我去看看其它可能的选择。

麻省理工公开课 - 化学原理课程节选

OK, so R minimum, the minimum separation occurs when the energy is at its minimum.

好的，所以R处是最小值，间距最小值出现在,当能量为最小的时候。

麻省理工公开课 - 固态化学导论课程节选