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(SAYING) Here at the GM battery lab, the Volt's 16 kilowatt lithium ion batteries are run through the rigors of extreme driving,weather fluctuations and abrupt movements.
VOA: standard.2010.07.30
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We started with gaseous sodium to make gaseous sodium ion and gaseous atomic chlorine to make gaseous chloride ion through electron transfer.
我们从气态的钠开始,得到气态的钠离子,从气态的氯原子,通过电子转移得到氯离子。
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And what I am going to do is say start with this ion, add up the energy associated with the interactions between that ion and everybody else in the row and then multiply it by Avogadro's number, because that is the number of atoms there are in a row.
接下来我要从这一离子开始，加上相互作用的能量，也就是这一离子,和其它所有在这一行的离子之间的能量,再乘以阿伏加德罗常数，因为这是在一行的原子的数量。
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So in the case of boron here, what we're starting with is the ion, and now we're going to pull one more electron out.
那么在硼的情况下，我们应该从这个离子开始，现在我们要再拿走一个电子。
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The one that's on the top here is called ligand-gated ion channel and an ion channel is a protein that sits in the surface of a cell.
最上面的这个叫作配体门控离子通道,离子通道是一类位于细胞表面的蛋白
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So now, let's get a sodium here, and the chloride ion next to it to the point where they are touching.
所以，我们要有一个钠离子，和氯离子放在,相互接触的一个点上。
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I have shown that by taking Avogadro's number of individual ion pairs and putting them all together in a line, the system's energy became more negative.
我推导出了,从每一个离子对中抽出阿伏加德罗常数,再把它们放在一起在一列中，这个系统的能量就变得更负。
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However, when that gate is opened, the sodium channel is now going to be incredibly selective and only let through sodium ions and no other type of ion.
但是，当闸门打开的时候，钠离子通道,将会有极高的选择性,不允许除钠离子以外的任何其它离子通过。
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So a plus two ion means that we're removing two electrons from the atom and the electrons that we're going to remove are always going to be the highest energy electrons.
一个2价正离子,我们要移除的两个电子,我们要移除的两个电子,将会是,最高能量的电子。
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And I know there's a lot to talk about this competition, but let's just get into listening mode here and talk about how we can figure out what the correct electron configuration is for this ion.
我知道刚才关于这次比赛大家有很多话要聊，但是请大家先转换到听讲的模式,来看看如何才能弄清楚,这个离子正确的电子排布。
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One plus one and then an ion pair grabs another one, another one.
加,接下来一对吸引另一对，再一对。
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And all ion channels are selective for a single type of ion, and we can think about how that selectivity takes place, and that's where this idea of atomic radius is going to become very important.
所有的离子通道都是仅对某一种离子具有选择性的，而我们可以来想一想这种选择性是如何发生的，这也就是原子半径这个概念将会变得，非常重要的地方。
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So, basically any time we have a really high positive number of electron affinity, it means that that atom or ion really wants to gain another electron, and it will be very stable and happy if it does so.
因此，基本上无论什么时候,只要我们有一个很大的正的电子亲和能，这就意味着这个原子,或离子非常希望得到一个电子，如果它得到了，会变得更稳定更开心。
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So, for example, let's look at thiocyanate ion, we have c s and n.
比如，让我们来看一下硫氰酸根离子，我们有碳，硫和氮。
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So, I've got ion pair formation, and I've got a huge decrease in energy because a donor is able to express that urge, an acceptor is able to express that urge.
所以我能得到形成的电子对，同时能量也大幅下降,因为失电子方要表达它的迫切，得电子方也要表达它的迫切。
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So, for example, if I have a sodium ion over here, and I have a chloride ion over here, where the distance from center to center r I'm denoting as r, this is nucleus to nucleus separation.
所以，比如这有一个钠离子，和一个氯离子，它们中心与中心间的距离,我把它设为，这是原子核和原子和的间距。
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It would generate an electrical signal because it would - you'd open the ion channel and you would ion fluxes and you would change the membrane potential in just the way I described for the action potential.
它会产生一个电信号,因为--,离子通道会打开,产生离子流,膜电位会改变,像我讲动作电位时那样
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And, we're going to look at what happens as the chloride ion moves from infinity in towards the positive ion.
然后我们要看一下,当氯离子从无限远处逐渐靠近,这个正离子会发生什么。
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So chlorine, if we talk about it in terms of electron affinity, we would be writing that we're actually gaining an electron here, and getting the ion, c l minus.
那么，氯，如果我们要讨论它的电子亲和能，我们会假设它真的得到了,一个电子而变成离子，负一价的氯。
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So, let's try another example here, and let's try a case now where instead of dealing with a neutral molecule we have an ion, so we have c n minus.
那么，让我们来试一下另外一个例子，这次不是一个中性原子,而是一个离子，氰离子。
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And they remain two atoms per ion pair discretely bombing around in the gas phase.
每个离子对中仍含有两个院子,分散得分布于气相中。
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And when we talk about any type of ion channel, there are just tons of different kinds of ion channels, and you can characterize them in a few different ways.
而当我们讨论任何一种离子通道时，离子通道有非常多种，你可以用几种不同的方法来描述它们。
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So the influx of ions from the outside of the cell to the inside of And you can think of ion channels as being gated, by gated it means the gate can be closed and no ions are going through, as in this case here.
下面以离子从细胞外部流入内部,你可以把离子通道想象成是有闸门的，也就是说闸门可以关上,这时没有离子能通过，就像这种情况。
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That's a very large number, it's all relative, so you don't necessarily know it's large without me telling you or giving you other ions to compare to, but chlorine does have a very large affinity, meaning it's really likes getting an electron and becoming a chlorine ion.
这是个非常大的数值，这种数值都是相对的，因此你不一定能知道这是非常大的,除非我告诉你或给你另外离子数值作为参考，但是氯确实有很高的电子亲和能，这意味着它非常乐意得到一个电子,而变成一个氯离子。
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So, for example, in an electrochemical cell, it would be possible to take the sodium ion, give back its electron, and convert it into a metallic sodium, take the chloride ion, remove its electron, and restore chlorine gas.
所以，例如一个电化学的电池，它可能带有钠离子，让它得到电子，把它变成金属钠，得到氯离子，让它失去电子，作为氯气储存。
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So if we consider lithium, potassium, and sodium, they're all together in the same group on the periodic table, knowing what we do about biology we can immediately think of sodium and potassium, or even just knowing what you know about table salt, for example, that these are two elements that we find, and particularly in the ion form in very high concentrations in our body.
我们来考虑一下锂，钾和钠，它们都在周期表中的同一族里，想要知道我们将元素周期律,用到生物学会怎么样，我们首先想到的就是钠和钾，甚至只需要知道食盐，我们发现它们是以很高浓度的离子形式,存在于我们体内的两种元素。
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So, in the case of boron plus 1, what we are starting with is the ion, so we're starting with a 2 s electron, 2 s 1 and then we're going to 2 s 1 here.
在正一价硼中，我们面对的是这个离子，本来就应该从，2，s，电子开始，然后这里变成。
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And it turns out that if we're talking about a 2 s orbital in an ion, that means it doesn't have as many electrons in it, so what we're going to see is less shielding.
结果是当我们讨论,一个离子中的，2，s，轨道的时候，这意味着里面没有多的电子，那么电子的屏蔽效应会更小。
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