I want to cool a gas with a Joule-Thomson experiment, what temperature do I have to be at?
给气体降温时,需要到达什么温度?
Another experiment would be to mix two chemicals together and put a thermometer in and measure the temperature.
比方说做这样一个试验,将两种化学试剂混合然后测定反应温度
And so an experiment said the gas didn't increase its temperature when it expanded the vacuum.
这个实验告诉你,气体在向真空膨胀的过程,中温度没有升高。
Joule actually did this experiment, and he observed that for the gas expansions that he could do, that the temperature did not increase measurably.
事实上焦耳的确做了这个实验,他做到了,他能达到的最好实验要求,发现在可测量范围内没有观察到温度上升。
It's tabulated in books, and this we can measure p in the experiment. Delta p here is the change in pressure from the left side to the right side, and we can put a thermometer, measure the temperature before the experiment and measure the temperature after the experiment.
这列在书上,这个量我们在,实验中也可以测量,在这里Δ,是从左边到右边的压强变化,我们可以放一个温度计,去测量实验前的温度,再去测量试验后的温度。
This is real, unlike the Joule coefficient which is very small so that most gases have tiny Joule coefficients. So if you do a Joule experiment, you hardly measure a temperature change. With real gases, here you do actually measure it. You can feel it with your finger on your bicycle tire.
系数那样小以至于,大多数气体的焦耳系数,都很小,所以如果你做焦耳实验,很难测量出温度的变化,对于真实气体,你可以测量它,你能通过手指按在,自行车轮胎上来感觉到它。
p This is going to get us dH/dp constant temperature. What is this experiment?
这帮助我们理解恒温条件下的偏H偏,那么这个实验具体是什么呢?
So in this experiment here, delta p is less than zero. You need to have this whole thing greater than zero. So delta T is less than zero as well. So if you're below the inversion temperature and you do the Joule-Thomson experiment, you're going to end up with something that's colder on this side than that side.
所以在这个实验中,Δp小于零,这全部都大于零,因此ΔT也小于零,所以如果在低于转变,温度的情况下做焦耳-汤姆孙实验,最后的结果是,这边的温度比这边低。
应用推荐