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And you would find that the bond energy of the heteronuclear molecule was nowhere on the average of the two.
你将发现,电子相同的分子的总能量,并不是平分的。
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This is the homonuclear bond energy for hydrogen in pure hydrogen. There we have perfect covalency.
这是氢的同原子的共价能,在纯氢中，我们有完美的共价键。
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So, there's actually another way to graph it where we can directly graph the dissociation energy or the bond strengths.
其实，还有另外一种画这个曲线的方式,可以直接画出离解能的大小,或者键的强度。
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If I'm going to be active in terms of managing my portfolio, should I spend my time and energy trying to beat the bond market?
如果我想主动地管理我的投资组合,是否应投入时间和精力,专注于战胜债券市场呢
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So the point is, this balance between energy thatyou could think of as say bond energies in chemical reactions, and entropy that you can think of in terms of disorder, how many different possible combinations or configurations of something wrong, will dictate where the equilibrium lies.
关键在于，这种能量与熵之间的平衡,确定了平衡的条件，在化学中能量涉及键能，而熵和无序有关,即有多少可能的不同组合或者形位，二者的平衡会告诉我们平衡态是什么样子。
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If you looked at heteronuclear molecules and you wanted to compute the bond energy, you might start with the bond energies of the two constituents.
如果你看那些相同电子的分子,你想计算共享能，你也许会从,两个组成部分的总能量。
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And you have the bond energy in HF.
你得到氟化氢的共价能。
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Well, you go look in your table So, if I had to guess, 4 what would you guess the bond energy would be in HF?
在你的表格里也有,如果让我们来猜猜，你会猜HF的键能是多少呢？
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In contrast, the dissociation energy of a bond for hydrogen, and molecular hydrogen is everywhere around us, we see 432 kilojoules per mole.
相反，氢分子在我们周围到处都是，一个氢分子的离解能，是432千焦每摩尔。
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It's much more relevant to set our zero point energy as the separation of a bond in terms of talking about the reactions that we'll usually be dealing with here.
更好的是把零点能定在,键断裂的时刻,在讨论化学反应的时候,而我们以后将经常遇到化学反应。
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But he said the energy of an X-Y bond is going to be equal to the square root.
但他说ＸＹ键的键能,会等于ＸＸ键与ＹＹ键键能乘积的平方根。
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So what we can actually directly compare is the dissociation energy or the bond strength of nitrogen versus hydrogen.
因此实际上我们可以直接进行比较,对氮分子与氢分子的离解能,或键的强度。
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And when we talk about covalent bonds, there's 2 properties that we'll mostly focus on, and that's going to be thinking about the bond strength or the energy by which it stabilized when it bonds.
而当我们讨论共价键的时候，有两点特性是我们最关注的，那就是键的强度,或者说成键之后能量降低了多少。
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So, another way to talk about dissociation energy is simply to call it bond strength, it's the same thing, they're equal to each other.
讨论离解能的另外一种方式,是直接称它为键的强度，它们是一样的，彼此相等。
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So, in talking about covalent bonds, we should be able to still apply a more general definition of a chemical bond, which should tell us that the h 2 molecule is going to be lower in energy than if we looked at 2 separate hydrogen atom molecules.
那么，既然提到了共价键，我们应该还可以,给化学键下一个更普遍的定义,那就是告诉我们氢分子能量应该更低,与两个分开的氢的单原子分子相比。
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If it's symmetric, that means that each bond has exactly the same energy.
这意味着如果他们对称，那么每根键的能量是一样的。
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If we know that this is it the dissociation energy for a hydrogen atom, we can also say the bond strength for hydrogen molecule 424 is 424.
如果我们知道了这是一个氢分子的离解能,那么我们也可以说氢分子的键的强度,就是。
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This energy level diagram helps us understand the relationship between electron filling and bond strength.
能级图能帮助我们,理解电子填充,和键强的关系。
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So, let's change our graph where we now have this zero point set as the two individuals hydrogen atoms, and then we see that our h 2 molecule is at the negative of the dissociation energy, or the negative what that bond strength is.
那么让我们把曲线图中的零点能改到,两个分离的氢原子处，那我们就会看到,氢分子就是负的离解能，或者负的键的强度。
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That is a lot of energy because there is a really solid bond.
这是很多的能量,因为这有一个真实固体键。
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So this is the energy of a single ionic bond.
这就是单离子键的能量。
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Or should I spend my time and energy trying to find the top quartile bond, top quartile real estate manager,or buyout manager, or venture capital manager?
还是说,我应该投入时间和精力,去找一流的债券经理人,一流的不动产或杠杆收购经理人,或者一流的风险投资经理人
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So, this gives you the energy of the bond.
这可以算出键能。
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More particularly, the HH bond, right, and let's ask what the energy of that is.
特别的是，HH键，让我们看看他的键能是多少。
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So, when we think about a bond length, this is going to be the length of our bond here, that makes sense because it's going to want to be at that distance that minimizes the energy.
因此，当我们考虑一个键的长度的时候，这就应该是我们的键长，这是合理的,因为体系会在核间距达到这一距离时,能量到达最小值。
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If you get some of these in the upper atmosphere, a photon, an ultraviolet photon, has the energy capable of breaking this bond.
如果你把它放到大气层上，一个光子，一个紫外光光子，有能量可以破坏它的化学键。
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So we know we always want to have our systems in as low an energy as possible, so it makes sense that a bond would happen any time we got a lower energy when we combine two atoms, versus when we keep them separate.
我们知道我们总是希望使我们的系统,处于能量尽可能低的状态，因此就应该有化学键产生,一旦我们合并两个原子之后体系的能量变得更低，相较于分开时。
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Same bond, symmetric bonds means equal energy, which means equal links.
相同的对称的化学键意味着相等的能量，相同的联系。
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OK, he also, let me see, he also, lastly, to close us out, he also developed an analytical expression for the energy of that covalent bond, which is really what we want.
好的，他也，让我看看，他也，最终接近我们的，他也发明了一种分析方式,对于共价键能量来说，这是我们真正想要的。
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So for b 2, which is a single bond, that's 289 kilojoules per mole to break it, and it takes us more energy to break this double bond for carbon, which is 599 kilojoules per mole.
对于B2，它是单键，需要289千焦每摩尔来打破它，而对于碳双键,打破它要更多的能量，等于599千焦每摩尔。
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