The difference of the average vibrational energy of solute molecules in the ground state at different temperature is a possible reason that induces this IVR time constants temperature dependence.
其中IVR过程与溶剂性质基本无关,由于受激发态富余振动能量大小的影响,在实验温度范围内随温度降低其时间常数呈线性增加。
The difference of the average vibrational energy of solute molecules in the ground state at different temperature is a possible reason that induces this IVR time constants temperature dependence.
其中IVR过程与溶剂性质基本无关,由于受激发态富余振动能量大小的影响,在实验温度范围内随温度降低其时间常数呈线性增加。
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