• At the same time, this paper also split the R-isomer of racemic to change and re-recovery.

    同时论文拆分R型异构体进行转变重回收。

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  • Mechanisms of the resolution of some of the racemic compounds on these bounded phases were proposed.

    本文部分化合物对映异构体拆分机制进行了初步探讨。

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  • Presently, most of the catalysts used for the resolution of racemic mixtures are hydrolases, especially lipases.

    目前用于拆分外消旋化合物多数水解酶,而且绝大多数为脂肪酶

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  • In many cases, racemic drug's single antipode has different curative effect, sometimes it even has adverse action.

    许多情况下,外药物中的单一对映体分别具有不同疗效有的甚至相反作用

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  • When considering biocatalysis, terms like kinetic racemic resolution or chiral syntheses immediately come to mind.

    提到生物催化,我们通常会想到旋物的动力学拆分手性合成

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  • The invention discloses a method for preparing racemic selenium-methyl selenocysteine by using aldehyde catalysis.

    发明公开了一种利用醛催化制备消旋硒-甲基硒代半胱氨酸的方法

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  • The amidocarbonylation reaction conditions were optimized and 66.4% isolated yield of racemic N-acetylleucine were obtained.

    文中对酰胺羰基化反应条件进行了优化,分离得到消旋N-乙酰基亮氨酸产率为66.4%。

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  • The membranes were then used in the electrodialysis resolution process to separate DL-4-hydroxyphenylglycine racemic mixture.

    将其用于拆分DL-羟基苯甘氨酸外混合物电渗析过程

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  • To develop a practical process for(R)-2-octanol production from racemic 2-octanol, a two step microbial reaction was investigated.

    建立一种新的制备手性2-醇的方法——双氧化还原耦联转化外2-辛醇制备(R)-2-辛醇。

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  • Use of stereoselective or stereospecific synthetic methods or separation of racemic mixtures can be used to obtain individual optical isomers.

    可以使用立体选择立体专一合成方法或者外消旋混合物分离获得单独光学异构体

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  • Optical resolution of racemic menthol has been efficiently achieved by lipase catalyzed enantioselective esterification in an organic solvent.

    利用脂肪酶有机溶剂中催化对映选择性酯化反应对外薄荷醇进行有效光学拆分

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  • The prepared polymers were applied as the liquid chromatographic chiral stationary phase to test their resolution ability for racemic carnitine hydrochloride.

    将所得聚合物用作高效液相色谱固定,研究了它们对外卡尼丁盐酸盐拆分能力

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  • The main route for obtaining optically active alcohols is resolution of racemic alcohols catalyzed by enzyme in organic solvents by the esterification reaction.

    有机相中应用酯化反应酶法催化拆分消旋获得光学活性重要途径

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  • The method has the advantages of convenient operation and low cost, and is suitable for the industrialized production of the racemic selenium-methyl selenocysteine.

    方法操作方便成本较低适合工业化生产消旋硒-甲基硒代半胱氨酸。

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  • The dynamic kinetic resolution (DKR) of racemic compounds provides one of the most convenient and efficient routes to a wide range of enantiomerically enriched molecules.

    动态动力学拆分是合成具有光学活性化合物方便有效方法之一

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  • Glycidyl butyrate was synthesized from racemic epichlorohydrin and butyric acid by chemical means. The purity of the refined product was over 96% and the yield was about 47%.

    利用化学方法外消旋环氧氯丙烷出发,合成丁酸环氧丙酯,精制后可获得纯度96%以上丁酸环氧丙酯,收率47%。

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  • In addition, the applications of enzyme-membrane bioreactors, especially in the resolution of racemic mixtures and the treatment of wastewater, have also been briefly discussed.

    此外,还对酶膜生物反应器尤其是对外消旋混合物拆分以及污水处理方面应用作了简要的介绍。

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  • Acetyl L carnitine was synthesized from racemic carnitine chloride and acetic acid by chemical means. The purity of the refined product was over 99% and the yield was about 96%.

    采用化学方法以肉为底物,合成了消旋乙酰肉碱,精制后可获得纯度99%以上乙酰肉碱,收率为96%。

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  • In this paper, we expediently, simply synthesized the racemic HPBA, prepared (r) -hpba which using chemical resolution and were engaged in studying the asymmetric synthesis of (?)

    课题的研究内容是方便简单地合成手性前体hpba采用化学拆分法制手性化合物(R) - HPBA,进行使用手性相转移催化剂不对称合成(?)

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  • The optimal enzyme resource, porcine pancreatic lipase(PPL), was confirmed by proper test in the resolution of racemic glycidol via esterification with a fatty acid in organic media.

    正交实验方法筛选出有机相中拆分环氧丙醇反应最适为猪脂肪酶PPL ) 。

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  • In conclusion, the new chiral derivatizing agent, AFGIT, is not only useful to resolve the racemic amine drugs or amino acids but also to enhance their detection sensitivity by the developed methods.

    结论,本研究所开发光学衍生AFGIT有效分离 混药物胺基并且增加它们侦测灵敏度

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  • The resolution of racemic compounds by crural inclusion complexation reported in 47 references is reviewed with 47 references. The chiral recognition principles in inclusion complex is also discussed.

    综述了手性拆分方法拆分外化合物中的应用,讨论了包结拆分中的手性识别原理参考文献47篇。

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  • Racemic ketoprofen was separated when the polymer was used as a stationary phase of high performance liquid chromatography. The mixture of ketoprofen and ibuprofen were also separated by this polymer.

    聚合物作为高效液相色谱固定消旋体酮洛固定相能分开同时聚合物还能将酮洛芬布洛混合物分开。

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  • Racemic ketoprofen was separated when the polymer was used as a stationary phase of high performance liquid chromatography. The mixture of ketoprofen and ibuprofen were also separated by this polymer.

    聚合物作为高效液相色谱固定消旋体酮洛固定相能分开同时聚合物还能将酮洛芬布洛混合物分开。

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