So that is the bond axis it's just the axis between the two nuclei.
这就是键轴,它就是两个原子核之间的轴。
But keep in mind sigma orbitals have no nodal planes along the bond axis.
但记住sigma轨道沿着,键轴方向是没有节点的。
Pi orbitals are a molecular orbital that have a nodal plane through the bond axis.
轨道是沿着键轴,有节面的分子轨道。
So any time you have two atoms bonding, the bond axis is just the axis that they're bonding along.
任何时候如果你有两个原子成键,键轴就是它们成键的方向。
Sigma symmetry of this molecular orbital, specifically that it's cylindrically symmetric about the bond axis.
告诉我们关于,And,the,sigma,tells,us,something,about,the,分子轨道对称性的信息,特别是它关于键轴是圆柱对称的。
So it's along the bond axis and it's between a carbon s p 2 hybrid, and then the hydrogen is just a 1 s orbital that we're combining here.
所以它是沿着键轴方向的,而且这里是一个碳sp2杂化轨道,和一个氢的1s轨道的结合,在这里我们可以合并他们。
So PI bonds have electron density both above and below the bond axis, but they actually have a nodal plane at this z, this bond axis here.
键在键轴之上,和之下都有电子密度,但它们在z方向有节面,这是键轴的地方。
Sigma as being cylindrically symmetric about the bond axis, and it's important to point out that it has no nodal plane across this bond axis.
键是,So, we,talk,about, a, sigma,bond,关于键轴圆柱对称的,需要着重指出的是,而且沿着键轴是没有节面的。
Remember this is our bond axis here, and you can see there is this area where the wave function is equal to zero all along that plane, that's a nodal plane.
记住这是我们的键轴,你可以看到在这些区域,波函数在这个面内全都是零,这是节点面。
But in sigma orbitals, you have no nodal planes along the bond axis, so if we had a nodal plane here, we'd see an area where the wave function was equal to zero.
但在sigma轨道里,沿着轴向是没有节点平面的,如果我们有个节点,我们就会看到某个地方波函数等于0。
The first one will be above and below the bond axis is where we'll see the electron density, and the second will be perpendicular to that, so it will be a density in front of and behind the bond axis.
第一个是在键轴之上和之下,我们可以看到电子密度,另外一个垂直于它,所以在键轴之前和之后有电子密度。
And a sigma bond forms any time you have two orbitals coming together and interacting on that internuclear axis.
当你把两个轨道合在一起,并在核间轴上有相互作用时,就形成了sigma键。
If we think about that, that's a sigma bond, right, they're coming together along the nuclear axis.
如果我们考虑它的话,它是sigma键,对吧,它们沿着核轴方向靠近。
Any time two orbitals come straight on together in that internuclear axis, you're going to have a sigma bond.
任何时候两个轨道,在核间轴上直接到一起,你就能得到sigma键。
A triple bond, again is going to have one sigma bond on the internuclear axis.
一个三键,同样的也有沿着核间轴sigma键。
In this paper, the tape, axis, blade and cutter disk are designed and calculated and the components of axle bearing and bond are selected.
本文分别对带、轴、刀片、刀盘等进行设计计算,对轴承、键等元件进行了选择。
In this paper, the tape, axis, blade and cutter disk are designed and calculated and the components of axle bearing and bond are selected.
本文分别对带、轴、刀片、刀盘等进行设计计算,对轴承、键等元件进行了选择。
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