这是原子轨道。
It's increased compared to the atomic orbitals.
相比原子轨道它应该更高。
Linear combination of atomic orbitals into molecular orbitals.
原子轨道的线性叠加,成分子轨道。
Standing wave representations such as these are called atomic orbitals.
这种驻波示意图叫做原子轨道。
So we would label our anti-bonding orbital higher in energy than our 1 s atomic orbitals.
我们应该把反键轨道标在,高于1s原子轨道能量的地方。
The 1 s just comes from the fact that the molecular orbital is a combination of two 1 s atomic orbitals.
是因为分子轨道是两个,1s原子轨道的组合。
Now, from your book as well, this is the pz's of the two atomic orbitals forming the bonding orbital.
现在,也是你们书上,这是两个pz轨道,组成的成键轨道。
And what you find is when you have a bonding orbital, the energy decreases compared to the atomic orbitals.
你们发现当你有个成键轨道的时候,相比原子轨道能量要降低。
So we can actually constructively and destructively combine these waves, these atomic orbitals to make a hybrid.
我们可以相长,和相消叠加这些波,这些原子轨道可以杂化。
So, let's think of the energy of interaction when we're comparing atomic orbitals to molecular bonding orbitals.
当我们比较原子轨道和分子轨道的时候,我们来考虑一下相互作用能。
So again, we can fill in our atomic orbitals here, there's going to be two electrons in each of our atomic orbitals.
同样的,我们可以填充原子轨道,每个原子轨道上有两个电子。
So, if we look at the molecular orbital, that's actually going to be lower in energy than either of the two atomic orbitals.
如果我们看分子轨道的话,它实际上要比,两个原子轨道都要低。
I am going to sum up the atomic orbitals that go into the molecular orbital, and they are going to have some coefficients.
我准备将原子轨道组合起来,进行分子轨道计算,这个过程还需添加一些系数。
It is also revealed that there are fairly strong interactions among the atomic orbitals of the three phenyl of fenvalerate.
通过数据还发现氰戊菊酯中的三个苯环的原子轨道间也存在较强的相互作用。
So again you can see as we're filling up our molecular orbitals, we're using the exact same principle we used to fill up atomic orbitals.
当我们填充轨道的时候可以看到,我们用的是和,填充原子轨道一样的原则。
A method based on a cluster model composed by pseudo-atomic orbitals is proposed for the calculation of deep energy levels in semiconductors.
本文提出了由赝原子轨道组成的集团计算半导体中深能级的方法。
In this paper, two type of wave function of zeroth degree for hydrogen molecule are constructed, starting from atomic orbitals of hydrogen in complex form.
本文从氢的复函原子轨道出发,构造了氢分子的两类零级波函数集。
There’s a radially symmetric blob, and a double-lobed blob with a node in the middle – just like the patterns of electron density that the s and p atomic orbitals give rise to.
右图中的球是围绕碳原子的电子云的图像。 它们分别是径向对称的球和中间有节点的双扁球形状,就像s和p原子轨道给出的电子密度图。
The first thing that I need to point out is you can actually see an n 2 versus o 2 that we flip-flopped N2 just like sometimes we had glitches in filling up our atomic orbitals.
我要指出的第一件事情就是,你们可以看到,和O2比,the,energy,of,the,sigma,and,the,pi,2,p,orbitals。,So,this,is,a,glitch,我们把sigma和π2p轨道,能量翻转过来了。
So, we'll start by taking a look at constructive interference, and another way to explain this is just to say again, molecular orbitals are a linear combination of atomic orbitals.
我们先来看一看相长干涉,另外一个解释它的方法就是说,分子轨道是原子轨道的组合。
And these orbitals arise from the combination of individual atomic orbital.
这些轨道起源于,每个原子轨道的组合。
Here is the atomic nitrogen, here is the atomic nitrogen and these are the orbitals of molecular nitrogen.
这是氮原子,这是氮原子,然后这是氮气的分子轨道。
So again, what we're talking about is the linear combination of atomic 2 p orbitals, and now we're talking about 2 p z.
同样,我们说的是,原子2p轨道的线性组合,现在我们我们说的是2pz。
So again, what we're talking about is the linear combination of atomic 2 p orbitals, and now we're talking about 2 p z.
同样,我们说的是,原子2p轨道的线性组合,现在我们我们说的是2pz。
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