研究了绝缘聚合物的化学结构对聚苯胺导电复合物形态结构及电性能影响。
The influence of the chemical structure of insulating polymer on the morphological structure and the electrical properties of polyaniline composite was investigated.
采用核壳乳液聚合方法合成了以甲基丙烯酸甲酯、 甲基丙烯酸和丙烯酸丁酯三元共聚物酸为核，聚苯胺为壳的导电高分子复合物。
Using emulsion polymerization, a conductive polymer composite was synthesized with polyaniline as shell , the polymer acid obtained by MMA MAA and BA as core.
结果表明，和氢溴酸对PANI的质子酸掺杂不同，溴掺杂过程中产生的溴负离子增加了PANI的载流子浓度，形成了电子转移复合物，提高了聚苯胺的电导率。
It is showed that bromine anions and charge transfer complex formed in the doping process enhanced the charge carrier concentration then promote the conductivity of PANI.
结果表明，和氢溴酸对PANI的质子酸掺杂不同，溴掺杂过程中产生的溴负离子增加了PANI的载流子浓度，形成了电子转移复合物，提高了聚苯胺的电导率。
It is showed that bromine anions and charge transfer complex formed in the doping process enhanced the charge carrier concentration then promote the conductivity of PANI.
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