研究了数种芳基甲烷在有机溶剂中碱催化下的氧化缩合反应,并对反应产物进行了表征。
Oxidative dimerizations of a seris of aryl methanes have been investigated and the products characterized.
本文报道在苯—氢氧化钠水溶液中,由苯酚和氯乙酸缩合制取苯氧乙酸的良好结果。
This work introduces nice results for the preparation of phenoxyacetio acid in benzene-sodium hydroxide aqueous system through condensation of phenol with chloroacetic acid.
以茶碱为原料经取代、氧化和缩合反应制备多索茶碱;其结构为IR及MS所证实。
Doxofylline was synthesized from theophylline by substitution, oxidation and condensation. The structure has been proven by IR and MS.
以前它是由碳水化合物发酵得到,现在由乙醛醛醇缩合或石油气体氧化的合成方法制得。
It was formerly derived by fermentation of carbohydrates but is now made synthetically by aldol condensation of acetaldehyde or by oxidation of petroleum gases.
丙酮酸的氧化能为催化量的琥珀酸所引发,说明有缩合酶的活性存在。
Pyruvate oxidation was accelerated by catalytic amount of succinate. The operation of condensing enzyme is thus indicated.
文章叙述了利用辐射接枝技术,缩合共价法,使葡萄糖氧化酶固定在聚乙烯、氟46膜上。
The paper is described the immobilization of GOD on polyethylene and F_ (46) by radiation grafting and condensation covalent.
方法:由葡萄糖通过缩合、氧化、去保护、酯化反应制备水杨酸葡萄糖酯。
Methods: Salicylic acid glucose esters were synthesized from glucose by condensation, oxidization, deprotection and esterification.
IR光谱分析同样反映出沥青经催化氧化后分子结构中侧链减少,芳环上的氢减少,整个芳环的缩合程度增加。
Meanwhile IR analysis showed that side chain between molecule and hydrogen of aromatic ring were decreased, condensed degree was increased in catalytic oxidation.
以苯甲醛和正庚醛为原料,乙二醇为溶剂,在氢氧化钾催化作用下羟醛缩合合成甲位戊基桂醛。
Amyl cinnamaldehyde was synthesized from benzaldehyde and n-heptanal by aldol condensation with catalyst potassium hydroxide in solvent ethylene glycol.
对愈疮木酚和乙醛酸缩合—氧化合成香兰素路线进行了中等规模的研究。
The manufacture of vanillin from guaiacol and glyoxylic acid was investigated in middle scale production.
本文论述的第一个内容是二氧化硒催化的缩合反应。
The first part of this dissertation is devoted to the study of selenium dioxide catalyzed condensation reactions.
发生在醛基上的反应主要有氧化、氢化、缩合、脱羰基等;
Occurred in the main reaction on the aldehyde oxidation, hydrogenation, condensation, de-carbonyl, etc.
非离子型表面活性剂有聚氧乙烯缩合物糖酯和烷基胺氧化物。
Nonionics include polyoxyethylene condensates, sucrose esters and alkyl amine oxides.
以氮杂环庚—2—酮和1—溴十二烷为原料合成氮酮,用氢氧化钾为反应缩合剂,PEG—400为相转移催化剂。
Synthesis of azone was carried out from azacycloheptan-2-one and 1-bromododecane using KOH as condensation agent and PEG-400 as phase transfer catalytic agent.
方法:以庚二酸单乙酯为原料,经酰氯化、傅克酰化、还原、水解、缩合及氧化反应合成塞曲司特。结果:塞曲司特的总产率为5 0 .7%。
Methods and results:Through acylation, Friedel Crafts reaction, reduction, hydrolysis, condensation and oxidation, the title compound was prepared with a total yield of 50.7%.
方法:以庚二酸单乙酯为原料,经酰氯化、傅克酰化、还原、水解、缩合及氧化反应合成塞曲司特。结果:塞曲司特的总产率为5 0 .7%。
Methods and results:Through acylation, Friedel Crafts reaction, reduction, hydrolysis, condensation and oxidation, the title compound was prepared with a total yield of 50.7%.
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