这样的碳原子称为手性碳。
这样的碳原子称为手性碳。
生物催化的还原反应能使分子内的羰基或碳-碳双键立体选择性的还原,将潜手性底物转化为手性产物,在不对称合成中有着重要的作用。
Biocatalytic reduction of the carbonyl groups or the carbon-carbon double bonds of the compounds has been utilized as a method for transforming the prochiral substrate into chiral product.
本文综述了手性膦配体及其碳碳双键的不对称催化氢化反应研究和最新进展,并对手性膦配体的设计做了分析和总结。
The paper reviewed the study on the chiral phosphines in asymmetric catalytic hydrogenation and their nearest development. Thedesign of chiral phosphines were also evaluated and summarized.
醇腈酶在化学合成中催化碳碳键的形成,其产物氰醇可以转化成多种重要的手性医药和农药中间体。
The hydroxynitrile lyases (HNLs) were used as catalyst for synthesis of enantiopure cyanohydrins which serve as versatile bifunctional building blocks for agro-and pharmaceutical intermediates.
首次研究了碳二亚胺14与手性氨基酸酯的成环反应,结果表明:在室温下,碳二亚胺14与手性氨基酸酯能快速成环生成一个五员环。
The cyclization reactions of carbodiimide 14 with chiral amide ethyl ester was firstly studied. The results showed that the carbodiimide 14 reacted quickly with amide ethyl ester at room temperature.
首次研究了碳二亚胺14与手性氨基酸酯的成环反应,结果表明:在室温下,碳二亚胺14与手性氨基酸酯能快速成环生成一个五员环。
The cyclization reactions of carbodiimide 14 with chiral amide ethyl ester was firstly studied. The results showed that the carbodiimide 14 reacted quickly with amide ethyl ester at room temperature.
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