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The Brazilian will now face Frenchman Arnaud Clement, who beat his Davis Cup team-mate Sebastien Grosjean 6-3 7-6.
BBC: Kuerten edges out Safin
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Callieri now faces French seventh seed Sebastien Grosjean , a 7-6 (7-2) 6-1 victor over Russia's Mikhail Youzhny .
BBC: Moya and Novak shake hands at the end of their match
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Tenth seed Carlos Moya booked his place in the end-of-season Masters Cup when he beat Frenchman Sebastien Grosjean 3-6 7-6 (12-10) 6-1.
BBC: Big names into quarter-finals
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Seventh seed Ferreira, 31, showed the form which helped him beat second seed Sebastien Grosjean and fifth seed Mark Philippoussis in earlier rounds.
BBC: Ferreira stuns Hewitt
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But Belgium's Xavier Malisse was forced to pull out of the eight-man round-robin tournament after retiring with a leg injury against Frenchman Sebastien Grosjean .
BBC: Safin, Ferrero ease through
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And Wimbledon champion Goran Ivanisevic is joined in the draw by Frenchman Sebastien Grosjean, who finished 2001 as world number six, and Australian Open finalist Marat Safin.
BBC: Hewitt heads Queen's Club entries
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American second seed Andy Roddick begins his campaign against Flavio Saretta of Brazil and is scheduled to face Sebastien Grosjean of France if both reach the last eight.
CNN: Venus set to face Henin-Hardenne
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The night matches saw victories for James Blake , who beat fellow American Todd Martin 6-1 3-6 7-5, and Sebastien Grosjean, who eased past David Sanchez 6-3 6-2.
BBC: Hewitt back from the brink