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An official World War I artist, Brangwyn was commissioned in 1924 to paint the murals for the Royal Gallery in the Palace of Westminster.
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Paintings for the exhibition have been loaned by the Tate, the Royal Academy and Manchester Art Gallery.
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It will be shown alongside Titian's two other known versions of John the Baptist, loaned from the Accademia gallery in Venice and the monastery at the former royal palace of El Escorial, near Madrid.
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The works in the latest presentation have been added to the Royal Collection, and will go on display at the Queen's Gallery, Buckingham Palace next autumn.
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His advice is sought at London's Tate Gallery (where he was a trustee) and at the Royal Academy, where in 1997 he curated a memorable Braque show.
ECONOMIST: 20th-century art
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Most of them were returned after 1815, but the French royal collection remained accessible in the Louvre, and it was in England, with spectacular private collections but no national gallery, that old-master exhibitions were first established.
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