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Italy's World Cup-winning captain Fabio Cannavaro, Brazilian midfielder Emerson and defenders Lilian Thuram and Gianluca Zambrotta have already departed for Spain.
BBC: SPORT | Football | Europe | Nedved decides to stay with Juve
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Suker put Miroslav Blazevic's side ahead, but a defensive error allowed right-back Lilian Thuram to equalise with his first ever goal for France.
BBC: Croatia's rise from obscurity
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Only three non-French based players made the initial list: Zinedine Zidane of Juventus, Lilian Thuram of Parma and Vincent Candela of AS Roma.
BBC: French to name new squad
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Henry joins Lilian Thuram, Marcel Desailly, Zinedine Zidane, Patrick Vieira and Didier Deschamps as the French players to have played 100 internationals or more.
BBC: Henry reaches 100-cap milestone
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Ronaldinho, Deco, Samuel Eto'o, Gianluca Zambrotta, Lilian Thuram, Xavi and Eidur Gudjohnsen were also among the players who arrived at the Nou Camp for a 9am start.
BBC: SPORT | Football | Henry to join Barca in Scotland