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Grosenick, a Baker Award finalist last year, allowed six goals on the first 12 shots.
WSJ: Quinnipiac earns Frozen Four bid, beats Union, 5-1
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He then stole an errant pass at center ice, moved down the right side and beat Grosenick with a snap shot at 10:59.
WSJ: Quinnipiac earns Frozen Four bid, beats Union, 5-1
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Grosenick, a finalist for last year's Hobey Baker Award, didn't have to be outstanding as his teammates outskated and outworked the Eagles (23-12-4).
WSJ: Union topples Boston College in NCAA tournament
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Peca, who recorded the first multiple-goal game of his college career and now has 15 tallies this season, beat Troy Grosenick with a backhander off a rebound scramble 9:46 in to start it off.
WSJ: Quinnipiac earns Frozen Four bid, beats Union, 5-1