And Hughes, 20, had a nightmare start, slashing at a short Steyn delivery off the fourth ball of the first over and only succeeding in getting a faint under-edge through to Mark Boucher.
Anderson's day did not begin auspiciously, however, as he dropped a regulation catch at slip to deny fellow England star Andrew Flintoff a fourth wicket when he found the edge of night-watchman Mark Davies's bat.
Ken Doherty recovered from 2-1 down to edge Nigel Bond 3-2, while Mark Williams was sunk 3-0 by Stuart Bingham in the season's first major tournament.
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Siddique, the 21-year-old left-hander, was eventually removed by Jacques Kallis, playing loosely outside off-stump to edge to wicketkeeper Mark Boucher.
The left-arm seamer then trapped Jacques du Toit lbw for a duck, leaving Leicestershire in disarray at 85 for five but Nixon, assisted by Tom New, at least managed to edge them nearer the follow-on mark of 159.
In helpful conditions for the bowlers, Chanderpaul arrived at the crease after Lancashire had lost Tom Smith to a catch at the wicket and Paul Horton to another at second slip off Balcombe - and immediately saw Mark Chilton edge behind.
The former pupil of Pontarddulais Comprehensive School provided a third catch for wicket-keeper Mark Wallace by finding the edge of Will Rudge's bat for his seventh wicket.
Forster who had the first real shot of the game on the five-minute mark, but his effort from the edge of the area was blocked by a Bradford defender.
Amin and fellow left-hander Fawad Alam shared an enterprising 141 for the second-wicket, which ended shortly before lunch when Amin pulled a Mark Lawson top-spinner and got a top-edge to mid-wicket.
After a clear run into the box he slipped a left-foot shot past Heaton from the edge of the six-yard box for a 2-0 lead and a goal to mark his 100th appearance in league football.
Their lack of cutting edge was ruthlessly punished by Argentina, who scored two tries in four minutes around the half-hour mark.
Only in the last 20 minutes did the limited Scots find anything resembling an attacking edge, and it resulted in replacement scrum-half Chris Cusiter's try just after the hour mark.
Dupuis followed by pouncing on a rebound off Mark Eaton's shot from the point to push Pittsburgh's edge to 4-0 and send Nabokov skating slowly to the bench in favor of Poulin.
The fifth-wicket partnership was worth 67 in 15.3 overs before Steve Harmison found Agarkar's edge, Mark Butcher taking a good diving catch at third man.
The only goal of the game came after Marc Smyth gathered the ball on the edge of the box and his mis-hit effort fell perfectly for Kean, who fired a curling shot past goalkeeper Mark Brown and into the net.
Kieswetter sliced straight to third man when on seven but survived because Morne Morkel was no-balled for over-stepping and South Africa's frustration was compounded as an edge by Pietersen edge bisected Jacques Kallis and keeper Mark Boucher, leaving the two veterans looking at each other and the ball flying to the boundary.
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