系统研究了脂肪甲酮与芳香醛和芳香胺参与的曼尼奇反应。
Mannich reactions with aromatic, aromatic ketones and aromatic aldehydes and their applications were studied systematically.
通过氧化反应可以由芳香族化合物得到酚、醛、酮、醌和羧酸等重要的有机中间体和精细化学品。
Phenols, aldehydes, ketones, quinones, carboxylic acids and many other important organic intermediates for fine chemicals can be obtained by oxidizing aromatic compounds.
醛、酮与醇的缩合反应是羰基保护的通用方法。
Condensation of aldehydes or ketones with alcohols is one of the most common methods for protecting carbonyls.
由(R)-丙叉甘油醛得到的手性亚胺1能与烯酮2在温和条件下迅速反应。
Chiral imine 1 derived from (r) glyceraldehyde acetonide could rapidly react with ketenes 2 which was converted from mixed anhydride or acid chloride under mild conditions.
在有机化学中,将苄卤和苄醇氧化成芳醛或芳酮是一类非常重要的反应。
In organic chemistry, the oxidation of benzyl halides and benzyl alcohols to aromatic aldehydes and aromatic ketones is an important reaction and of great significance both in theory and in practice.
在有机合成中,芳环化合物的氯甲基化和将苄基卤氧化成芳醛或芳酮是一类极其重要的反应。
In organic synthesis, chloromethylation of aromatic compounds and oxidation of benzylic halides to aromatic aldehydes or aromatic ketones are extremely important reactions.
在非质子性溶剂,镁对频纳醇与醛和酮的还原耦合反应也有一定效果。
In aprotic solvents magnesium effects pinacol reductive coupling of aldehydes and ketones.
各种含有酮或醛的芳基三氟甲磺酸酯在催化量的钯和膦配体的存在下与胺或酰胺发生取代反应。
Various aryl triflates, bearing ketone or aldehyde groups, were evaluated for palladium-mediated introduction of an amino group at the triflate position in the presence of various phosphine ligands.
表面的伯胺基在与茚三酮反应后转化为醛基,通过银镜反应证明了醛基的存在。
The surface amino group was transferred to the aldehyde group after it reacted with ninhydrin. The surface aldehyde group was confirmed by the mirror reaction.
羟基处于醛基邻位和对位的苯甲醛与几种苯乙酮衍生物的缩合,多数没有得到预期的产物,或收率极低;苯乙酮环上的羟基对缩合反应影响很大,羟基越多,缩合越困难。
The groups in ring of benzaldehydes, no matter they are electron withdrowing or electron donating except of hydroxy, do not seem to have much effect on the yield.
羟基处于醛基邻位和对位的苯甲醛与几种苯乙酮衍生物的缩合,多数没有得到预期的产物,或收率极低;苯乙酮环上的羟基对缩合反应影响很大,羟基越多,缩合越困难。
The groups in ring of benzaldehydes, no matter they are electron withdrowing or electron donating except of hydroxy, do not seem to have much effect on the yield.
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